Plate-making method, plate-making apparatus, computer- to- cylinder type lithographic printing method and computer- to- cylinder type lithographic printing apparatus

ABSTRACT

Disclosed is a plate-making method and a computer-to-cylinder type lithographic printing method, each of which comprises filtering an oil-based ink; forming an image directly on a plate material by an ink jet process comprising ejecting said filtered oil-based ink using electrostatic field based on signals of image data; and fixing said formed image to prepare a printing plate. Also disclosed are a plate-making apparatus and a computer-to-cylinder type lithographic printing method suitable for these methods, respectively.

FIELD OF THE INVENTION

[0001] The present invention relates to a plate-making method and a plate-making apparatus, which perform digital plate-making by an electrostatic ink jet process using an oil-based ink, and also relates to a computer-to-cylinder type lithographic printing method and a computer-to-cylinder type lithographic printing apparatus, which perform the above-described digital plate-making on the printing apparatus and subsequently performing printing. More specifically, the present invention relates to a plate-making method, a plate-making apparatus, a computer-to-cylinder type lithographic printing method and a computer-to-cylinder type lithographic printing apparatus, where the oil is filtered before use and thereby, the image on the printing plate and the printed image are improved in the quality.

BACKGROUND OF THE INVENTION

[0002] In the lithographic printing, the printing is performed by forming an ink-receptive region and an ink-repulsive region on the surface of a printing plate in correspondence to an image original and adhering a printing ink to the ink-receptive region. Usually, hydrophilic and lipophilic (ink-receptive) regions are imagewise formed on the surface of a printing plate and the hydrophilic region is rendered ink-repulsive using a fountain solution.

[0003] In general, the formation of an image (plate-making) on a printing original plate (plate material) is heretofore performed by a method of once outputting an image original on a silver salt photographic film in an analog or digital manner, exposing a diazo resin or photopolymerizable photopolymer light-sensitive material (plate material) through the film and then, dissolving and removing the non-image area using an alkaline developer.

[0004] In recent years, the lithographic printing method is demanded to meet requirements for more improvement in the digital drawing technique and higher efficiency in the process thereof and in view of these recent requirements, a large number of systems for directly recording digital image information have been proposed. These techniques are called CTP (computer-to-plate) or DDPP (digital direct printing plate), With respect to the plate-making method, for example, a system of recording an image in the light or heat mode using a laser has been proposed and this system is partially put into practical use.

[0005] However, even in this plate-making method, irrespective of light mode or heat mode, the plate-making generally involves a treatment with an alkaline developer after the laser recording to dissolve and remove the non-image area, therefore, an alkaline waste solution is discharged and this is not preferred in view of the environmental conservation.

[0006] In the method of using a laser, an expensive and large-scale apparatus is necessary. In this respect, a system applying an ink jet process which is an inexpensive and compact recording device, has been proposed.

[0007] JP-A-64-27953 (the term “JP-A” as used herein means an “unexamined published Japanese patent application”) discloses a method of forming an image on a hydrophilic plate material by an ink jet process using a lipophilic wax ink, thereby performing plate-making. In this method, the image is formed by a wax and therefore, the image area is weak in the mechanical strength and deficient in the adhesive property to the hydrophilic surface of the plate material, which gives rise to poor press life.

[0008] As means for realizing an efficient printing process, a system of performing the image formation on a printing apparatus is known. JP-A-4-97848 discloses a method of providing a plate drum having a hydrophilic or lipophilic surface area in place of a conventional plate cylinder, forming thereon a lipophilic or hydrophilic image by an ink jet process, and removing and cleaning the image after the completion of printing. In this method, however, it is difficult to attain easy removing (namely, cleaning) of the printed image and a sufficiently long press life at the same time. Furthermore, in the case of forming an image having high press life on the plate drum, an ink containing a resin in a relatively high concentration must be used and accompanying the evaporation of solvent at the nozzle part, the resin readily fixes to the ink jet means of forming a printing image, as a result, the ink ejection stability decreases and a good image cannot be obtained.

[0009] In the case of forming an image by an ink jet process, aggregates in the ink or foreign matters such as dust fed to the ejection head cause clogging of the head and this gives rise to unstable ejection of ink and in turn deterioration in the image quality or stopping of the ejection. The present invention has been made to overcome these problems.

SUMMARY OF THE INVENTION

[0010] An object of the present invention is to provide a plate-making method for manufacturing a lithographic printing plate which ensures printing of a large number of printed matters having a clear and high-quality image by an inexpensive and simple process, where a development processing is not necessary and a digital technique can be adopted.

[0011] Another object of the present invention is to provide a plate-making apparatus for realizing this plate-making method.

[0012] A still other object of the present invention is to provide a computer-to-cylinder type lithographic printing method capable of blocking flowing of aggregates or foreign matters such as dust and always feeding an ink kept in a normal state to an ejection head, where a development processing is not necessary and a digital technique can be adopted.

[0013] A still other object of the present invention is to provide a computer-to-cylinder type lithographic printing apparatus for realizing this computer-to-cylinder type lithographic printing method.

[0014] A still other object of the present invention is to provide a computer-to-cylinder type lithographic printing method capable of printing a large number of printed matters having a clear and high-quality image by an inexpensive apparatus and a simple and easy method.

[0015] A still other object of the present invention is to provide a computer-to-cylinder type lithographic printing apparatus for realizing this computer-to-cylinder type lithographic printing method.

[0016] Other objects and effects of the present invention will become apparent from the following description.

[0017] The above-described objects of the present invention have been achieved by providing the following methods and apparatuses.

[0018] 1) A plate-making method comprising:

[0019] filtering an oil-based ink;

[0020] forming an image directly on a plate material by an ink jet process comprising ejecting said filtered oil-based ink using electrostatic field based on signals of image data; and

[0021] fixing said formed image to prepare a printing plate.

[0022] 2) The plate-making method according to item 1) above, wherein said oil-based comprises:

[0023] a nonaqueous solvent having an electric resistivity of 10⁹ Ωcm or more and a dielectric constant of 3.5 or less; and

[0024] a component dispersed in the nonaqueous solvent, comprising at least resin particles which are solid and are hydrophobic at least at ordinary temperatures.

[0025] 3) A plate-making apparatus comprising:

[0026] an image-forming unit which forms an image directly on a plate material based on signals of image data; and

[0027] an image-fixing unit which fixes the image formed by said image-forming unit to prepare a printing plate,

[0028] wherein said image-forming unit comprises an ink jet drawing device having an ejection head which ejects an oil-based ink using electrostatic field and having at least one ink-filtering member provided in a passage of said oil-based ink.

[0029] 4) The plate-making apparatus according to item 3) above, wherein said filtering member is provided at a portion immediately preceding an ink ejection part of said ejection head.

[0030] 5) The plate-making apparatus according to item 3) or 4) above, wherein said filtering member comprises a filter material which blocks coarse aggregates of said oil-based ink and foreign matters including dust mingled during the image formation.

[0031] 6) The plate-making apparatus according to item 5) above, wherein said filter material has pores having various shapes and sizes, each of said pores having a minimum distance of not less than 2 μm.

[0032] 7) The plate-making apparatus according to item 5) or 6) above, wherein said filter material has a single-layer or multilayer structure.

[0033] 8) The plate-making apparatus according to item 7) above, wherein said multilayer filter material comprises filter material layers including; a coarsest protective body and a coarsest support provided in an upstream side and a downstream side, respectively; and intervening filter material layers provided between said protective body and support in such a manner that the pore sizes of said intervening filter materials are sequentially reduced toward the downstream side.

[0034] 9) The plate-making apparatus according to any one of items 5) to 8) above, wherein said filter material has at least one figuration selected from the group consisting of a single plate form, a tea strainer form, a coming back form and a cylinder form.

[0035] 10) The plate-making apparatus according to any one of items 5) to 9) above, wherein said filter material comprises at least one material selected from the group consisting of paper, plastic, metal, ceramic and glass.

[0036] 11) The plate-making apparatus according to any one of items 5) to 10) above, wherein said filter material is of cartridge-type and exchangeable.

[0037] 12) The plate-making apparatus according to any one of items 5) to 11) above, further comprising a filter material accumulation-removing member which removes substances accumulated on said filter material.

[0038] 13) The plate-making apparatus according to item 12) above, wherein said removal of the filter material accumulation is performed by at least one of ultrasonic irradiation, vibration, and back flow of said ink or a cleaning solution.

[0039] 14) The plate-making apparatus according to item 3) or 4) above, wherein said filtering member comprises at least one filtering system selected from the group consisting of gravity filtration, pressure filtration, vacuum filtration and constant rate filtration.

[0040] 15) The plate-making apparatus according to any one of items 3) to 14) above, wherein said oil-based ink comprises:

[0041] a nonaqueous solvent having an electric resistivity of 10⁹ Ωcm or more and a dielectric constant of 3.5 or less; and

[0042] a component dispersed in the nonaqueous solvent, comprising at least resin particles which are solid and are hydrophobic at least at ordinary temperatures.

[0043] 16) The plate-making apparatus according to any one of items 3) to 15) above, wherein said image-fixing unit has a heating member comprising at least one of a heat roller, an infrared lamp, a halogen lamp and a xenon lamp.

[0044] 17) The plate-making apparatus according to item 16) above, wherein said heating member is disposed and/or controlled to gradually elevate a temperature of said plate material at the time of said fixing.

[0045] 18) The plate-making apparatus according to any one of items 3) to 17) above, further comprising a drum for mounting said plate material thereon, said drum being rotatable to perform main scanning upon said image formation.

[0046] 19) The plate-making apparatus according to item 18) above, wherein said ejection head comprises a single channel head or a multi-channel head and is movable in a direction parallel to the axis of said drum to perform sub-scanning upon said image formation.

[0047] 20) The plate-making apparatus according to any one of items 3) to 17) above, further comprising at least a pair of capstan rollers for running said plate material while being interposed and held therebetween to perform sub-scanning upon said image formation.

[0048] 21) The plate-making apparatus according to item 20) above, wherein said ejection head comprises a single channel head or a multi-channel head and is movable in a direction orthogonal to the running direction of said plate material to perform main scanning upon said image formation.

[0049] 22) The plate-making apparatus according to item 18) or 20) above, wherein said ejection head comprises a full line head having almost the same length as the width of said plate material.

[0050] 23) The plate-making apparatus according to any one of items 3) to 22) above, wherein said ink jet drawing device has an ink feed member which feeds said oil-based ink to said ejection head.

[0051] 24) The plate-making apparatus according to item 23) above, which comprises an ink recovery member which recovers said oil-based ink from said ejection head to circulate said ink.

[0052] 25) The plate-making apparatus according to any one of items 3) to 24) above, which comprises a dust-removing member which removes dusts present on the surface of said plate material at least one of before and during said image formation.

[0053] 26) The plate-making apparatus according to any one of items 3) to 25) above, wherein said ink jet drawing device has an ink tank for storing said oil-based ink and a stirring member which stirs the oil-based ink in said ink tank.

[0054] 27) The plate-making apparatus according to any one of items 3) to 26) above, wherein said ink jet drawing device has an ink tank for storing said oil-based ink and an ink temperature-controlling member which controls the temperature of the oil-based ink in said ink tank.

[0055] 28) The plate-making apparatus according to any one of items 3) to 27) above, wherein said ink jet drawing device has an ink concentration-controlling member which controls the concentration of said oil-based ink.

[0056] 29) The plate-making apparatus according to any one of items 3) to 28) above, which comprises an ejection head-cleaning member.

[0057] 30) A computer-to-cylinder type lithographic printing method comprising:

[0058] mounting a plate material onto a plate cylinder of a printing apparatus;

[0059] filtering an oil-based ink;

[0060] forming an image directly on said plate material by an ink jet process comprising ejecting said filtered oil-based ink from an ejection head using electrostatic field based on signals of image data;

[0061] fixing said image to prepare a printing plate; and

[0062] performing lithographic printing with said printing plate.

[0063] 31) The computer-to-cylinder type lithographic printing process according to item 30) above, wherein said oil-based ink comprises:

[0064] a nonaqueous solvent having an electric resistivity of 10⁹ Ωcm or more and a dielectric constant of 3.5 or less; and

[0065] a component dispersed in the nonaqueous solvent, comprising at least resin particles which are solid and are hydrophobic at least at ordinary temperatures.

[0066] 32) A computer-to-cylinder type lithographic printing apparatus comprising:

[0067] a plate cylinder;

[0068] an image-forming unit which directly forms an image on a plate material mounted onto said plate cylinder based on signals of image data;

[0069] an image-fixing unit which fixes the image formed by said image-forming unit to prepare a printing plate; and

[0070] a lithographic printing unit which performs lithographic printing with the printing plate,

[0071] wherein said image-forming unit comprises an ink jet drawing device having an ejection head which ejects an oil-based ink using electrostatic field and having at least one ink filtering member provided in a passage of said oil-based ink.

[0072] 33) The computer-to-cylinder type lithographic printing apparatus according to item 32) above, wherein said filtering member is provided at a portion immediately preceding an ink ejection part of said ejection head.

[0073] 34) The computer-to-cylinder type lithographic printing apparatus according to item 32) or 33) above, wherein said filtering member comprising a filter material which blocks coarse aggregates of said ink and foreign matters including dust mingled during the image formation.

[0074] 35) The computer-to-cylinder type lithographic printing apparatus according to item 34) above, wherein said filter material has pores having various shapes and sizes, each of said pores having a minimum distance of not less than 2 μm.

[0075] 36) The computer-to-cylinder type lithographic printing apparatus according to item 34) or 35) above, wherein said filter material has a single-layer or multilayer structure.

[0076] 37) The computer-to-cylinder type lithographic printing apparatus according to item 36) above, wherein said multilayer filter material comprises filter material layers including: a coarsest protective body and a coarsest support provided in an upstream side and a downstream side, respectively; and intervening filter material layers provided between said protective body and support in such a manner that the pore sizes of said intervening filter materials are sequentially reduced toward the downstream side.

[0077] 38) The computer-to-cylinder type lithographic printing apparatus according to any one of items 34) to 37) above, wherein said filter material has at least one figuration selected from the group consisting of a single plate form, a tea strainer form, a coming back form and a cylinder form.

[0078] 39) The computer-to-cylinder type lithographic printing apparatus according to any one of items 34) to 38) above, wherein said filter material comprises at least one material selected from the group consisting of paper, plastic, metal, ceramic and glass.

[0079] 40) The computer-to-cylinder type lithographic printing apparatus according to any one of items 34) to 39) above, wherein said filter material is of cartridge-type and exchangeable.

[0080] 41) The computer-to-cylinder type lithographic printing apparatus according to any one of items 34) to 40) above, further comprising a filter material accumulation-removing member which removes substances accumulated on said filter material.

[0081] 42) The computer-to-cylinder type lithographic printing apparatus according to item 41) above, wherein said removal of the filter material accumulation is performed by at least one of ultrasonic irradiation, vibration, and back flow of said ink or a cleaning solution

[0082] 43) The computer-to-cylinder type lithographic printing apparatus according to item 32) or 33) above, wherein said filtering member comprises at least one filtering system selected from the group consisting of gravity filtration, pressure filtration, vacuum filtration and constant rate filtration.

[0083] 44) The computer-to-cylinder type lithographic printing apparatus according to any one of items 32) to 43) above, wherein said oil-based ink comprises:

[0084] a nonaqueous solvent having an electric resistivity of 10⁹ Ωcm or more and a dielectric constant of 3.5 or less; and

[0085] a component dispersed in the nonaqueous solvent, comprising at least resin particles which are solid and are hydrophobic at least at ordinary temperatures.

[0086] 45) The computer-to-cylinder type lithographic printing apparatus according to any one of items 32) to 44) above, wherein said image-forming unit comprises a dust-removing member which removes dusts present on the surface of the plate material at least one of before and during said image formation.

[0087] 46) The computer-to-cylinder type lithographic printing apparatus according to any one of items 32) to 44) above, wherein said plate cylinder is rotatable to perform main scanning upon said image formation.

[0088] 47) The computer-to-cylinder type lithographic printing apparatus according to item 46) above, wherein said ejection head comprises a single channel head or a multi-channel head and is movable in a direction parallel to the axis of said plate cylinder to perform sub-scanning upon said image formation.

[0089] 48) The computer-to-cylinder type lithographic printing apparatus according to item 46) above, wherein said ejection head comprises a full line head having almost the same length as the width of said plate material.

[0090] 49) The computer-to-cylinder type lithographic printing apparatus according to any one of items 32) to 48) above, wherein said ink jet drawing device has an ink feed member which feeds said oil-based ink to said ejection head.

[0091] 50) The computer-to-cylinder type lithographic printing apparatus according to item 49) above, which comprises an ink recovery member which recovers said oil-based ink from said ejection head to circulate said ink.

[0092] 51) The computer-to-cylinder type lithographic printing apparatus according to any one of items 32) to 50) above, which comprises an ink tank for storing said oil-based ink and an ink-stirring member which stirs the oil-based ink in said ink tank.

[0093] 52) The computer-to-cylinder type lithographic printing apparatus according to any one of items 32) to 51) above, which comprises an ink tank for storing said oil-based ink and an ink temperature-controlling member which controls the temperature of the oil-based ink in said ink tank.

[0094] 53) The computer-to-cylinder type lithographic printing apparatus according to any one of items 32) to 52) above, which comprises an ink concentration-controlling member which controls the concentration of said oil-based ink.

[0095] 54) The computer-to-cylinder type lithographic printing apparatus according to any one of items 32) to 53) above, wherein said ink jet drawing device has an ejection head-retreating/approximating member which approximates said ejection head to said plate cylinder upon said image formation and retreats said ejection head from said plate cylinder except for during image formation.

[0096] 55) The computer-to-cylinder type lithographic printing apparatus according to any one of items 32) to 54) above, wherein said image-forming unit has an ejection head-cleaning member which cleans said ejection head at least at the completion of plate-making.

[0097] 56) The computer-to-cylinder type lithographic printing apparatus according to any one of items 32) to 55) above, wherein said lithographic printing unit has a paper dust-removing member which removes paper dusts generated during said lithographic printing.

[0098] According to the plate-making apparatus of item 3) above, a filter for ink is inserted between the ink tank and the ejection head, so that foreign matters in the ink can be blocked from flowing into the ejection head and occurrence of unstable ejection state can be prevented.

[0099] According to the plate-making apparatus of item 4) above, the filter is disposed immediately before the ejection head, so that a clean ink immediately after the filtering can be fed to the ejection head.

[0100] According to the plate-making apparatus of item 5) above, the ink feed device of the ink jet drawing device filters aggregates of ink or foreign matters mingled on the way, such as dust, by a filter and feeds a normal ink to the ejection head, so that ejection in an unstable state due to clogging of the ejection head and troubles due to unstable ejection at the drawing, namely, changes in the dot size or deterioration of the image such as slipping or thinning of the image, can be prevented.

[0101] According to the plate-making apparatus of item 6) above, pores different in the shape and the size are present together in the same filter material, so that various foreign matters can be effectively filtered and the ink can be filtered without causing reduction in the filtering rate.

[0102] According to the plate-making apparatus of item 7) above, a filter is used as a single layer or a plurality of filters are stacked to form a multilayer structure, so that the filter can be properly used according to the purpose, for example, a single-layer (for example, single plate-type) filter is used in the case where the ink has good quality and the filtering rate is important as in the disposition immediately before the ejection heat, whereas a multilayer-typo filter ensuring high filtering power, scarce clogging and use for a long period of time is disposed in the pump side because a pump pressure or the like is necessary so as not to reduce the filtering rate.

[0103] According to the plate-making apparatus of item 8) above, a filter having a coarse pore size is disposed in the ink inflow side to roughly filter the ink and remove main foreign matters, and a dense filter is disposed in the next stage to completely remove foreign matters, so that filtration can be effectively performed over a long period of time without causing reduction in the filtering rate.

[0104] According to the plate-making apparatus of item 9) above, the filter can be selected from filters having various forms such as a simple single-plate form, an inline-type tea strainer form capable of taking out and cleaning or exchanging only a filter element on the way, a coming back form of performing circulation filtering through the filter layer divided into a plurality of layers, and a cylinder form including multilayer type and hollow yarn type, by taking account of the quality or volume of ink or conditions such as place for installation or construction or performance of the apparatus.

[0105] According to the plate-making apparatus of item 10) above, the construction material of the filter is selected from materials over a wide range by taking account of the use end, such as paper for use having high frequency of exchange or disposal, membrane-type plastic (polymer) material obtained by bundling many hollow plastic yarns to have a cross section of hollow yarn-type filter like a hollow yarn film, metal of wire-mesh type or obtained by stacking and sintering stainless steel metal fiber felts and usable for a long term when washed or cleaned, glass and ceramic.

[0106] According to the plate-making apparatus of item 11) above, a hollow yarn-type or multilayer cylinder-type filter for use in a water purifier or the like can be exchanged together with the cartridge housing the filter by a simple and quick operation and in the case of a tea strainer-type (T-type inline) filter, only the element itself can be taken out and returned after cleaning or exchanged while allowing the filter to remain on the line.

[0107] According to the ink feed device of the ink jet drawing device in item 12) above, means for cleaning the filter material is provided, so that cleaning and removal can be performed automatically or appropriately by hand at a predetermined timing (for example, every 300 hours of operation).

[0108] According to the plate-making apparatus of item 13) above, the accumulation can be removed by means of ultrasonic irradiation or vibration applied to the filter and in addition, by back flow of ink or cleaning solution. In the case of a hollow yarn-type filter, efficient cleaning can be attained by back flow from the water outlet side to the water inlet side.

[0109] According to the plate-making apparatus of item 14) above, the filtration is performed by flowing the ink under a pressure resultant from combining gravity filtration using a gravity of the ink itself, pressure filtration using a pump pressure and vacuum filtration using a vacuum pump pressure, so that the filtration can be efficiently performed without causing reduction in the filtering rate (ink flow rate). A pump pressure of the ink feed part, circulation part, tank or the like may also be used as the pressure.

[0110] According to the computer-to-cylinder type lithographic printing method of item 30) above, the oil-based ink is used after filtering it, so that foreign matters in the ink flowing to the ejection head can be blocked and the ejection in a stable state can be attained.

[0111] According to the computer-to-cylinder type lithographic printing apparatus of item 32), a filter is inserted between the ink tank and the ejection head, so that foreign matters in the ink to the ejection head can be blocked and unstable ejection can be prevented from occurring.

[0112] According to the construction in item 33) above, the filter is disposed in particular immediately before the ejection head, so that a clean in immediately after the filtering can be fed to the ejection head.

[0113] According to the construction in item 34) above, aggregates of ink and foreign matters such as dust mingled on the way are filtered by a filter and a normal ink is fed to the ejection head, so that ejection in an unstable state due to clogging or the like of the ejection head can be prevented and troubles due to unstable ejection at the drawing, namely, changes in the dot size or deterioration of the image such as slipping or thinning of the image, can be prevented.

[0114] According to the construction in item 35) above, pores different in the shape and the size are present together in the same filter material, so that foreign matters having various shapes and sizes can be effectively filtered and the ink can be filtered without causing reduction in the filtering rate.

[0115] According to the construction in item 36) above, a filter is used as a single layer, or a plurality of filters are stacked to form a multilayer structure, so that the filter can be properly used according to the purpose, for example, a single-layer (for example, single plate-type) filter is used in the case where the ink has good quality and the filtering rate is important as; in the disposition immediately before the ejection heat, whereas a multilayer-type filter ensuring high filtering power, scarce clogging and use for a long period of time is disposed in the pump side because a pump pressure or the like is necessary so as not to reduce the filtering rate.

[0116] According to the construction in item 37) above, a filter having a coarse pore size is disposed in the ink inflow side to roughly filter the ink and remove main foreign matters, and a dense filter is disposed in the next stage to completely remove foreign matters, so that filtration can be effectively performed over a long period of time without causing reduction in the filtering rate.

[0117] According to the construction in item 38) above, the filter can be selected from filters having various forms such as a simple single-plate form, an inline-type tea strainer form capable of taking out and cleaning or exchanging only a filter element on the way, a coming back form of performing circulation filtering through the filter layer divided into many layers, and a cylinder form including multilayer type and hollow yarn type, by taking account of the quality or volume of ink or conditions such as place for installation or construction or performance of the apparatus.

[0118] According to the construction in item 39) above, the construction material of the filter is selected from materials over a wide range by taking account of the use end, such as paper for use having high frequency of exchange or disposal, membrane-type plastic (polymer) material obtained by bundling many hollow plastic yarns to have a cross section of hollow yarn-type filter like a hollow yarn film, metal of wire-mesh type or obtained by stacking and sintering stainless steel metal fiber felts and usable for a long term when washed or cleaned, glass and ceramic.

[0119] According to the construction in item 40) above, a hollow yarn-type or multilayer cylinder-type filter for use in a water purifier or the like can be exchanged together with the cartridge housing the filter by a simple and quick operation and in the case of a tea strainer-type (T-type inline) filter, only the element itself can be taken out and returned after cleaning or exchanged while allowing the filter to remain on the line.

[0120] According to the construction in item 41) above, means for cleaning the filter material is provided, so that cleaning and removal can be performed automatically or appropriately by hand at a predetermined timing (for example, every 300 hours of operation).

[0121] According to the construction in item 42) above, the accumulation can be removed by means of ultrasonic irradiation or vibration applied to the filter and in addition, by back flow of ink or cleaning solution. In the case of a hollow yarn-type filter, efficient cleaning can be attained by the back flow from the water outlet side to the water inlet side.

[0122] According to the construction in item 43) above, the filtration is performed by flowing the ink under a pressure resultant from combining gravity filtration using a gravity of the ink itself, pressure filtration using a pump pressure and vacuum filtration using a vacuum pump pressure, so that the filtration can be efficiently performed without causing reduction in the filtering rate (ink flow rate). A pump pressure of the ink feed part, circulation part, tank or the like may also be used as the pressure.

BRIEF DESCRIPTION OF THE DRAWINGS

[0123]FIG. 1 is an entire construction view schematically showing one example of the plate-making apparatus for use in the present invention.

[0124]FIG. 2 is an entire construction view schematically showing another example of the plate-making apparatus for use in the present invention.

[0125]FIG. 3 is a view schematically showing one example of the drawing part of the plate-making apparatus for use in the present invention.

[0126]FIG. 4 is a construction view of an apparatus where an ink-circulating function is added.

[0127]FIG. 5 is a schematic construction view showing one example of the ejection head provided in the ink jet drawing device for use in the present invention.

[0128]FIG. 6 is a schematic cross-sectional view showing the vicinity of the ink ejection part of FIG. 5.

[0129]FIG. 7 is a schematic cross-sectional view showing the vicinity of the ink ejection part in another example of the ejection head provided in the ink jet drawing device for use in the present invention.

[0130]FIG. 8 is a schematic front view showing the vicinity of the ink ejection part of FIG. 7.

[0131]FIG. 9 is a schematic constitution view showing main parts in another example of the ejection head provided in the ink jet drawing device for use in the present invention.

[0132]FIG. 10 is a schematic constitution view of the ejection head of FIG. 9 from which regulating plates are removed.

[0133]FIG. 11 is a schematic constitution view showing main parts in another example of the ejection head provided in the ink jet drawing device for use in the present invention.

[0134] FIGS. 12(a) and 12(b) are explanatory views of pores of a filter 60.

[0135]FIG. 13 is a perspective view of a multilayer-type filter.

[0136]FIG. 14 is a cross-sectional view of a single plate-type filter.

[0137]FIG. 15 is a cross-sectional view of a tea strainer-type filter.

[0138]FIG. 16 is an explanatory view of a coming back-type filter.

[0139]FIG. 17 is an entire construction view schematically showing one example of the computer-to-cylinder type lithographic printing apparatus for use in the present invention.

[0140]FIG. 18 is an entire construction view schematically showing the computer-to-cylinder type four-color one-side lithographic printing machine for use in the present invention.

DETAILED DESCRIPTION OF THE INVENTION

[0141] The present invention is described in detail below.

[0142] In the present invention, an image is formed on a plate material by an electrostatic ink jet process of ejecting an oil-based ink using an electrostatic field.

[0143] The electrostatic ink jet process according to the present invention is described, for example, in PCT Publication WO93/11866. In this electrostatic ink jet process, an ink having high resistance obtained by dispersing at least resin particles which are solid at ordinary temperatures and hydrophobic, in an insulating solvent is used, a strong electric field is allowed to act on this ink at the ejection position to form an aggregate of the resin particles at the ejection position, and the aggregate is ejected from the ejection position using electrostatic means. In this way, the resin particles are ejected as an aggregate formed to a high concentration and therefore, the printed dots can have a sufficiently large thickness, as a result, the image of aggregated resin particles formed on the printing plate can have sufficiently long press life.

[0144] In this ink jet process, the size of the ink droplet ejected is determined by the size of the distal end of the ejecting electrode or the conditions in forming the electric field. Therefore, a small ink droplet can be obtained without reducing the ejection nozzle size or slit width and the dot size on the plate material can be controlled by controlling the conditions in forming an electrical field.

[0145] In other words, according to the present invention, a fine image having a sufficiently long press life can be controlled without causing any problem of ink clogging in the head and a large number of printed matters having a clear image can be printed.

[0146] The construction example of the plate-making apparatus for practicing the plate-making method of the present invention is described below.

[0147]FIGS. 1 and 2 each is an entire construction view of a plate-making apparatus. FIGS. 3 and 4 are views schematically showing a construction example of the plate-making apparatus including the control part, ink feed part and head-retreating/approximating mechanism. FIGS. 5 to 11 each is a view for explaining an ink jet drawing device of a plate-making apparatus of FIGS. 1 and 2.

[0148] The plate-making process according to the present invention is described using an entire construction view of a plate-making apparatus having a structure such that a plate material is mounted onto a drum 11 shown in FIG. 1. However, the present invention is not limited to the following construction example.

[0149] The drum 11 is usually made of a metal such as aluminum, stainless steel and iron, a plastic, a glass or the like. Particularly, in the case of a metal-made drum, the surface thereof is subjected to, for example, alumite treatment or chromium plating in many cases, so as to intensify the abrasion resistance. The drum 11 may have a heat insulating material on the surface thereof as described later. The drum 11 preferably has an earth function to act as a counter electrode of the ejection head electrode at the electrostatic injection. In the case where the substrate of the plate material has high insulating property, an electrically conducting layer is preferably provided on the substrate and in this case, means for taking the earth is preferably provided in this electrically conducting layer. Also in the case of providing a heat insulating material on the drum 11, the drawing may be facilitated by providing means for taking the earth on the plate material and for this purpose, known means having electrical conductivity, such as brush, leaf spring or roller may be used.

[0150] The plate-making apparatus 1 further has an ink jet drawing device 2 which ejects an oil-based ink on the plate material (printing original plate) 9 mounted onto the drum 11 in correspondence to the image data sent from an image data arithmetic and control part 21 and forms an image.

[0151] The plate-making apparatus 1 further has a fixing device 5 for strengthening the oil-based ink image drawn on the plate material 9. If desired, a plate surface desensitizing device 6 may be provided for the purpose of intensifying the hydrophilicity on the surface of the plate material 9. The plate-making apparatus 1 further has dust-removing member 10 of removing dusts present on the surface of the plate material 9 before and/or during the drawing on the plate material 9. By this means, the ink can be effectively prevented from adhering to the plate material 9 by the help of dusts invaded between the head and the plate material during the plate-making and thereby, good plate-making can be attained. For the dust-removing member 10, a known non-contact method such as suction removal, blowing removal or electrostatic removal, or a contact method by a brush, a roller or the like may be used. In the present invention, air suction, air blowing or a combination thereof is preferably used.

[0152] Furthermore, an automatic plate feed device 7 of automatically feeding the plate material 9 to the drum 11 and an automatic plate discharge device 8 of automatically removing the plate material 9 from the drum 11 after the completion of drawing may be provided. By using these automatic plate feed device 7 and automatic plate discharge device 8, the plate-making operation is more facilitated and the plate-making time can be shortened, as a result, the effect of the present invention is more elevated.

[0153] The process of preparing a printing plate using the plate-making apparatus 1 is described below by referring to FIG. 1 and partially to FIG. 3.

[0154] A plate material 9 is mounted onto the drum 11 using an automatic plate feed device 7. At this time, the plate material 9 is tightly fixed on the drum 11 by a mechanical method using a known plate head/edge gripping device, an air suction device or the like, or by an electrostatic method, so that the edge of plate can be prevented from fluttering to come into contact with the ink jet drawing device 2 during the drawing and cause damages. Furthermore, means of tightly contacting the plate material 9 to the drum 11 only in the periphery of the drawing position of the ink jet drawing device 2 may be provided and by actuating this at least at the time of performing the drawing, the plate material 9 can be prevented from contacting with the ink jet drawing device 2. To speak specifically, for example, a method of disposing a presser roller upstream and downstream the drawing position on the drum 11 may be used. In the case of not performing the drawing, the head is preferably kept apart from the plate material, whereby the ink jet drawing device 2 can be effectively prevented from generation of troubles such as damage by contact.

[0155] The image data arithmetic and control part 21 receives image data from an image scanner, a magnetic disc device, an image data transmission device or the like, performs color separation, if desired, and then partitions and computes the separated data into an appropriate number of picture elements or an appropriate number of gradations. Furthermore, since the oil-based ink image is drawn as a dotted image using an ejection head 22 (see, FIG. 3; this is described in detail later) of the ink jot drawing device 2, the halftone dot area factor is also computed. In addition, as described layer, the image data arithmetic and control part 21 controls the movement of the ejection head 22, the timing of ejecting the oil-based ink and if desired, the timing of operating the drum 11 and the like.

[0156] These data computed and input in the image data arithmetic and control part 21 are once stored in a buffer. The image data arithmetic and control part 21 rotates the drum 11 and approximates the ejection head 22 to the position proximate to the drum 11 using a head-retreating/approximating device 31. The ejection head 22 and the surface of the plate material 9 on the drum 11 are kept at a predetermined distance during the drawing using mechanical distance controlling member such as knock roller or under the control of the head-retreating/approximating device based on the signals from an optical distance detector. By virtue of this distance control, good plate-making can be performed without causing non-uniformity in the dot size due to floating of the plate material or without causing any change in the dot size particularly even when vibration is applied to the plate-making machine.

[0157] For the ejection head 22, a single channel head, a multi-channel head or a full line head may be used. The main scanning is performed by the rotation of the drum 11. In the case of a multi-channel head having a plurality of ejection parts or a full line head, the array direction of the ejection parts is set to the axial direction of the drum 11. Furthermore, in the case of a single channel head or a multi-channel head, the image data arithmetic and control part 21 moves the ejection head 22 in the direction parallel to the axis of the drum 11 every each rotation of the drum 11 and an oil-based ink is ejected to the plate material 9 mounted onto the drum 11 based on the ejection position and the halftone dot area factor obtained by the computation. By this ejection, a halftone image is drawn by the oil-based ink according to the variable density of the printing original. This operation continues until an oil-based ink image of one color portion of the printing original is formed on the plate material 9 and a printing plate is finished. On the other hand, in the case where the ejection head 22 is a full line head having almost the same length as the width of the drum 11, an oil-based ink image of one color portion of the printing original is formed on the plate material 9 by one rotation of the drum 11 and thereby a printing plate is finished. As such, the main scanning is performed by the rotation of the drum 11, whereby the positional precision in the main scanning direction can be elevated and high-speed drawing can be attained.

[0158] The ejection head 22 is retreated to come apart from the position proximate to the drum 11 so as to protect the ejection head 22. This retreating/approximating member is operated to separate the ejection head at least 500 μm or more apart from the drum except for the drawing time. The retreating/approximating operation may be performed by a slide system or in a pendulum manner by fixing the ejection head 22 using an arm fixed to a certain axis and moving the arm around the axis. By retreating the ejection head 22 at the non-drawing time, the ejection head 22 can be protected from the physical breakage or contamination and can have a long life.

[0159] The oil-based ink image formed is intensified by a fixing apparatus 5. For fixing the ink, known means such as heat-fixing or solvent fixing may be used. In the heat-fixing, hot air fixing by the irradiation of an infrared lamp, a halogen lamp or a xenon flash lamp or using a heater, or heat-roller fixing is generally employed. In this case, the fixing property can be elevated by using individually or in combination the means such as preheating of the plate material 9, drawing while applying hot air, coating of the drum 11 with a heat insulating material, and heating of only the plate material 9 by separating the plate material 9 from the drum 11 at the fixing. The flash fixing using a xenon lamp or the like is known as a fixing method of electrophotographic toner and this is advantageous in that the fixing can be performed within a short time. In the case of using a paper plate material having provided with plastic thin layers on its front and back surfaces as water resisting layers, the water content inside the plate material abruptly evaporates due to the abrupt elevation of the temperature and a phenomenon called blister of generating asperities on the surface of the plate material takes place. Therefore, it is preferred to gradually elevate the temperature of the paper plate material by gradually increasing the power supply to the heat source while rotating the drum 11 or by changing the rotational speed from high to low with a constant power supply. The temperature of the paper plate material may be gradually elevated by disposing a plurality of fixing machines in the rotational direction of the drum 11 and varying the distance from these to the plate material 9 and/or the supplied electric power.

[0160] In the solvent fixing, a solvent capable of dissolving the resin components in the ink, such as methanol and ethyl acetate, is sprayed or the plate material is exposed to the solvent vapor while recovering excess solvent vapor.

[0161] At least in the process from the formation of an oil-based ink image by the ejection head 22 until the fixing by the fixing apparatus 5, the image on the plate material 9 is preferably kept not to come into contact with any thing.

[0162] A construction example of the plate making apparatus which performs the sub-scanning by running a plate material 9 is described below using FIG. 2, however, the present invention is not limited to the following construction example.

[0163] A plate material 9 is transported while being interposed and held between two pairs of captain rollers 16. Using data partitioned and computed into appropriate number of picture elements and number of gradations by an image data arithmetic and control part 21, an image is drawn by an ink jet drawing device 2. In the position where an image is drawn by the ink jet drawing device 2, earth means 17 is preferably provided to work out to a counter electrode of the ejection head electrode at the time of electrostatic ejection, whereby the drawing is facilitated. In the case where the substrate of the plate material 9 has high insulating property, an electrically conducting layer is preferably provided on the substrate and in this case, this electrically conducting layer is preferably earthed by known means having electrical conductivity, such as brush, leaf spring or roller.

[0164]FIG. 1 and FIG. 2 each show an apparatus where a sheet plate material is used. However, a roll plate material is also suitably used and in this case, a sheet cutter is preferably provided upstream the automatic plate feed device. The plate-making apparatus further has an ink jet drawing device 2 which ejects an oil-based ink on the plate material 9 in correspondence to the image date sent from the image data arithmetic and control part 21 and forms an image.

[0165] The plate-making apparatus 1 further has a fixing device 5 for strengthening the oil-based ink image drawn on the plate material 9, If desired, a plate surface desensitizing device 6 may be provided for the purpose of intensifying the hydrophilicity on the surface of the plate material 9. The plate-making apparatus 1 further has dust-removing member 10 of removing dusts present on the surface of the plate material before and/or during the drawing on the plate material 9. By this means, the ink can be effectively prevented from adhering to the plate material by the help of dusts invaded between the ejection head and the plate material during the plate-making and thereby, good plate-making can be attained. For the dust-removing member 10, a known non-contact method such as suction removal, blowing removal or electrostatic removal, or a contact method by a brush, a roller or the like may be used. In the present invention, air suction, air blowing or a combination thereof is preferably used.

[0166] Furthermore, an automatic plate feed device 7 of automatically feeding the plate material 9 and an automatic plate discharge device 8 of automatically removing the plate material 9 after the completion of drawing are preferably provided. By using these automatic plate feed device 7 and automatic plate discharge device 8, the plate-making operation is more facilitated and the plate-making time can be shortened, as a result, the effect of the present invention is more elevated.

[0167] The process of preparing a printing plate using the plate-making apparatus 1 is described below by referring to FIG. 2 and partially to FIG. 3.

[0168] A plate material 9 is transported using an automatic plate feed device 7 and captain rollers 16. At this time, if desired, printing material guide means (not shown) may be provided so as to prevent the head/edge of the plate material from fluttering and contacting with an ink jet drawing device 2 to cause damages. Furthermore, means of preventing loosening of the plate material 9 only in the periphery of the drawing position of the ink jet drawing device 2 may be provided and by actuating this means at least at the time of performing the drawing, the plate material 9 can be prevented from contacting with the ink jet drawing device 2. To speak specifically, for example, a method of disposing a presser roller upstream and downstream the drawing position may be used. In the case of not performing the drawing, the ejection head is preferably kept apart from the plate material 9, whereby the ink jet drawing device 2 can be effectively prevented from generation of troubles such as damage by contact.

[0169] The image data from a magnetic disk device or the like is given to an image data arithmetic and control part 21 and according to the input image data, the image data arithmetic and control part 21 computes the position of ejecting an oil-based ink and the halftone dot area factor at that position. These computed data are once stored in a buffer.

[0170] The image data arithmetic and control part 21 moves the ejection head 22, controls the timing of ejecting the oil-based ink and the timing of operating the capstan rollers, and if desired, approximates the ejection head 22 to the position proximate to the plate material 9 using a head-retreating/approximating device 31.

[0171] The ejection head 22 and the surface of the plate material 9 are kept at a predetermined distance during the drawing using mechanical distance controlling member such as knock roller or under the control of the head-retreating/approximating device based on the signals from an optical distance detector. By virtue of this distance control, good plate-making can be performed without causing non-uniformity in the dot size due to floating of the plate material or without causing any change in the dot size particularly even when vibration is applied to the plate-making machine.

[0172] For the ejection head 22, a single channel head, a multi-channel head or a full line head may be used and the sub-scanning is performed by the transportation of the plate material. In the case of a multi-channel head having a plurality of ejection parts, the array direction of ejection parts is set to be almost parallel to the running direction of the plate material. Furthermore, in the case of a single channel head or a multi-channel head, the ejection head 22 is moved in the direction orthogonal to the running direction of the plate material 9 by the image data arithmetic and control part 21 every each movement of the plate material and an oil-based ink is ejected to the plate material 9 at the ejection position and at the halftone dot area factor obtained by the computation. By this ejection, a halftone image is drawn by the oil-based ink according to the variable density of the printing original. This operation continues until an oil-based ink image of one color portion of the printing original is formed on the plate material 9 and a printing plate is finished. On the other hand, in the case where the ejection head 22 is a full line head having almost the same length as the width of the plate material 9, the array direction of ejection parts are set to the direction almost orthogonal to the running direction of the plate material and an oil-based ink image of one color portion of the printing original is formed on the plate material 9 by passing the plate material 9 through the drawing part, thereby finishing a printing plate.

[0173] The ejection head 22 is preferably retreated to come apart from the position proximate to the plate material 9 so as to protect the ejection head 22. This retreating/approximating member is operated to separate the ejection head at least 500 μm or more apart from the plate material 9 except for the drawing time. The retreating/approximating operation may be performed by a slide system or in a pendulum manner by fixing the ejection head using an arm fixed to a certain axis and moving the arm around the axis. By retreating the ejection head at the non-drawing time, the ejection head can be protected from the physical breakage or contamination and can have a long life.

[0174] The oil-based ink image formed is intensified by a fixing apparatus 5. For fixing the ink, known means such as heat-fixing or solvent fixing may be used. In the heat-fixing, hot air fixing by the irradiation of an infrared lamp, a halogen lamp or a xenon flash lamp or using a heater, or heat-roller fixing is generally employed. The flash fixing using a xenon lamp or the like is known as a fixing method of electrophotographic toner and this is advantageous in that the fixing can be performed within a short time. In the case of using a paper plate material having provided with plastic thin layers on its front and back surfaces as water-resisting layers, the water content inside the plate material abruptly evaporates due to the abrupt elevation of the temperature and a phenomenon called blister of generating asperities on the surface of the plate material takes place. Therefore, for preventing the blister of the plate material 9, it is preferred to dispose a plurality of fixing machines and gradually elevate the temperature of the paper plate material by changing the power supply and/or the distance from the fixing machine to the plate material 9.

[0175] In the solvent fixing, a solvent capable of dissolving the resin components in the ink, such as methanol and ethyl acetate, is sprayed or the plate material is exposed to the solvent vapor while recovering excess solvent vapor.

[0176] At least in the process from the formation of an oil-based ink image by the ejection head 22 until the fixing by the fixing apparatus 5, the image on the plate material 9 is preferably kept not to come into contact with any thing.

[0177] The obtained printing plate is subjected to printing by a known lithographic printing process. More specifically, the printing plate having formed thereon the oil-based ink image is mounted onto a printing apparatus, a printing ink and a fountain solution are given thereto to form a printing ink image, the printing ink image is transferred to a blanket cylinder rotating together with the plate cylinder and subsequently, the printing ink image on the blanket cylinder is transferred to a printing paper sheet passing through between the blanket cylinder and an impression cylinder, thereby performing printing of one color portion, After the completion of printing, the printing plate is removed from the plate cylinder and the blanket on the blanket cylinder is cleaned by a blanket cleaning device to provide a state where next printing can be performed.

[0178] The ink jet drawing device 2 is described below.

[0179] As shown in FIG. 3, the ink jet drawing device 2 for use in the plate-making apparatus comprises an ink jet ejection head 22 and an ink feed part 24. The ink feed part 24 further comprises an ink tank 25, an ink feed pump 26, a filter 60 (which is described in detail later) as ink filtering means, and ink concentration-controlling member 29 and in the ink tank 25, stirring member 27 and ink temperature-controlling member 28 are contained. The ink may be circulated in the ejection head 22 as described later and in this case, the ink feed part 24 additionally has a recovery and circulating function. The stirring member 27 prevents the precipitation and coagulation of solid contents in the ink and reduces the need for cleaning of the ink tank 25. For the stirring member 27, a rotary blade, an ultrasonic vibrator and a circulation pump may be used and these are used individually or in combination. The ink temperature-controlling member 28 is disposed such that the physical properties of ink or the dot size does not vary by the change of the ambient temperature and a high-quality image can be stably formed. For the ink temperature-controlling member, a known method may be used, for example, a method where a heat-generating element or a cooling element such as heater or Peltier device is disposed within the ink tank 25 together with the stirring member 27 and the temperature distribution within the ink tank 25 is controlled constant by a temperature sensor such as thermostat. The ink temperature within the ink tank 25 is preferably from 15 to 60° C., more preferably from 20 to 50° C. The stirring member for maintaining the temperature distribution within the ink tank 25 to be constant may be used commonly with the stirring member for preventing the precipitation or coagulation of solid components in ink.

[0180] As shown in FIG. 4, the ink feed device 24 takes a system of circulating ink. The ink feed part 24 has, as shown in FIG. 4, an ink tank 25 storing an oil-based ink 23, a valve 61, a pump 26 for feeding an ink to an ejection head 22, ink concentration-controlling member 29 and a filter 60, and has a recovery and circulating function by a pump 26′ and a valve 61′ for circulating and recovering the ink from the head 22. In FIG. 4, the filter 60 is disposed immediately before the ejection head 22 and therefore, a more clean ink can be fed to the ejection head 22.

[0181] For drawing a high-quality image, the apparatus preferably has ink concentration-controlling member 29. By having this means, generation of bleeding on the plate or slipping or thinning of the printed image due to reduction in the solid concentration in the ink, or change in the dot size on the plate due to increase in the solid concentration, can be effectively prevented. The ink concentration is controlled by measuring the physical properties using, for example, optical detection, measurement of electrical conductivity or measurement of viscosity, or by counting the number of plates subjected to the drawing. In the case of controlling the ink concentration by measuring the physical properties, an optical detector, an electrical conductivity-measuring meter and a viscosity-measuring meter are provided individually or in combination within the ink tank 25 or on the passage of ink and according to the output signals thereof, the feed of liquid to the ink tank 25 from a concentrated ink tank (not shown) for replenishment or from a diluting ink carrier tank is controlled. In the case of controlling the ink concentration by counting the number of plates subjected to the drawing, the feed of liquid is controlled by the number of plates manufactured and the frequency of plate-making.

[0182] The image data arithmetic and control part 21 computes the input image data and moves the ejection head 22 using a head-retreating/approximating device 31 or head sub-scanning means 32, as described above, and additionally takes in the timing pulse from an encoder 30 disposed in the drum 11 or a capstan roller and drives the ejection head 22 according to the timing pulse. By this, the positional precision is elevated.

[0183] The ejection head 22 is described below using FIGS. 5 to 11, however, the present invention is not limited thereto.

[0184]FIGS. 5 and 6 each is a view showing one example of the ejection head provided in the ink jet drawing device. The ejection head 22 has a slit between an upper unit 221 and a lower unit 222 each comprising an insulating substrate, and the distal end of the slit works out to an ejection slit 22 a. Within the slit, an ejection electrode 22 b is disposed and the slit is filled with an ink 23 fed from the ink feed device. Examples of the insulating substrate which can be used include plastics, glass and ceramics. The ejection electrode 22 b is formed by a known method, for example, a method of subjecting the lower unit 222 comprising an insulating substrate to vapor deposition, sputtering or electroless plating with an electrically conductive material such as aluminum, nickel, chromium, gold and platinum, coating a photoresist thereon, exposing the photoresist through a predetermined electrode pattern mask, developing it to form a photoresist pattern of the ejection electrode 22 b and etching the pattern, a method of mechanically removing the photoresist pattern or a method comprising a combination thereof.

[0185] As shown in FIG. 5, a drum 11 which works out to a counter electrode is provided to oppose the ejection electrode 22 b provided in the ejection head 22 and on the drum 11 as the counter electrode, a plate material 9 is provided. When a voltage is applied to the ejection electrode 22 b according to digital signals of the image pattern information, a circuit is formed between the ejection electrode 22 b and the drum 11 as the counter electrode, and an oil-based ink 23 is ejected from the ejection slit 22 a of the head 22 to form an image on the plate material 9 provided on the drum 11 as the counter electrode.

[0186] With respect to the width of the ejection electrode 22 b, the tip thereof is preferably as narrow as possible for forming a high-quality image. The specific numerical value varies according to the conditions such as applied voltage and physical properties of ink but the tip width is usually from 5 to 100 μm.

[0187] For example, a dot of 40 μm can be formed on the plate material 9 by using an ejection electrode 22 b having a tip width of 20 μm, providing a distance of 1.0 mm between the ejection electrode 22 b and the drum 11 as the counter electrode, and applying a voltage of 3 KV between these electrodes for 0.1 msec.

[0188]FIGS. 7 and 8 are a schematic cross-section view and a schematic front view, respectively, showing the vicinity of the ink ejection part in another example of the ejection head. In the Figures, 22 is an ejection head and this ejection head 22 has a first insulating substrate 33 having a tapered shape. Opposing the first insulating substrate 33, a second insulating substrate 34 is provided with a clearance and at the distal end of the second insulating member 34, an inclined face part 35 is formed. The first and second insulating substrates each is formed of, for example, plastic, glass or ceramic. On the upper face part 36 making an acute angle with respect to the inclined face part 35 of the second insulating substrate 34, a plurality of ejection electrodes 22 b are provided as means for forming an electrostatic field in the ejection part. Respective tips of these multiple ejection electrodes 22 b are extended to the vicinity of the distal end of the upper face part 36 and the tips each is projected ahead of the first insulating substrate 33 to form an ejection part. Between the first and second insulating substrates 33 and 34, an ink inflow passage 37 is formed as means for feeding an ink 23 to the ejection part and in the lower side of the second insulating substrate 34, an ink recovery passage 38 is formed. The ejection electrode 22 b is formed on the second insulating substrate 34 in the same manner as above by a known method using an electrically conducting material such as aluminum, nickel, chromium, gold and platinum. Individual electrodes 22 b are constructed to lie in the electrically insulating state from each other.

[0189] The tip of the ejection electrode 22 b is preferably projected to the length of 2 mm or less from the distal end of the insulating substrate 33. The projection length is preferably within this range because if the projection length is excessively large, the ink meniscus does not reach the tip of the ejection part, as a result, the ejection of ink becomes difficult or the recording frequency decreases. The space between the first and second insulating substrates 33 and 34 is preferably from 0.1 to 3 mm. The space is preferably within this range because if the space is too small, the feed and in turn ejection of ink become difficult or the recording frequency decreases, whereas if the space is excessively large, the meniscus is not stabilized and the ejection becomes unstable.

[0190] The ejection electrode 22 is connected to the image data arithmetic and control part 21 and in performing the recording, a voltage is applied to the ejection electrode based on the image information, the ink on the ejection electrode is ejected and an image is drawn on a plate material (not shown) disposed to oppose the ejection part. In the direction opposite the ink droplet-ejecting direction of the ink inflow passage 37, the ink feed member of the ink feed device (not shown) is connected. On the surface opposite the ejection electrode-formed surface of the second insulating substrate 34, a backing 39 is provided to oppose the ejection electrode with a clearance. Between the ink feed member and backing, an ink recovery passage 38 is provided, The ink recovery passage 38 preferably has a space of 0.1 mm or more. The space is preferably within this range because if the space is too small, the recovery of ink becomes difficult and ink leakage may occur. The ink recovery passage 38 is connected to the ink recovery member of the ink feed device (not shown).

[0191] In the case where a uniform ink flow is necessary on the ejection part, a groove 40 may be provided between the ejection part and the ink recovery part. FIG. 8 is a schematic front view showing the vicinity of the ink ejection part of the ejection head. On the inclined face of the second insulating substrate 34, a plurality of grooves 40 are provided to extend from the vicinity of the boundary with the ejection electrode 22 b toward the ink recovery passage 38. These grooves 40 in plurality are aligned in the array direction of the ejection electrodes 22 b and each has a function of introducing a constant amount of ink in the vicinity of the tip of the ejection electrode through the opening in the ejection electrode 22 b side by a capillary force according to the opening diameter and discharging the introduced ink to the ink recovery passage 38. Therefore, the grooves each has a function of forming an ink flow having a constant liquid thickness in the vicinity of the ejection electrode tip. The shape of the groove 40 may be sufficient if the capillary force can work, but the width is preferably from 10 to 200 μm and the depth is preferably from 10 to 300 μm. The grooves 40 are provided in the number necessary for forming a uniform ink flow throughout the head.

[0192] With respect to the width of the ejection electrode 22, the tip of the ejection electrode 22 b is preferably as narrow as possible for forming a high-quality image. The specific numerical value varies depending on the applied voltage, physical properties of ink or the like, however, the tip width is usually from 5 to 100 μm.

[0193]FIGS. 9 and 10 each is a view showing another example of the ejection head used for practicing the present invention. FIG. 9 is a schematic view showing only a part of the head for purpose of explanation. As shown in FIG. 9, the ejection head 22 comprises a head body 41 formed of an insulating material such as plastic, ceramic or glass, and meniscus regulating plates 42 and 42′. In the Figures, 22 b is an ejection electrode for applying a voltage and thereby forming an electrostatic field in the ejection part. The head body is described in detail below by referring to FIG. 10 where the regulating plates 42 and 42′ are removed.

[0194] In the head body 41, a plurality of ink grooves 43 for circulating the ink are provided perpendicularly to the edge of the head body. The shape of the ink groove 43 may be sufficient if the capillary force can work and thereby a uniform ink flow can be formed, but the width of the ink groove is preferably from 10 to 200 μm and the depth is preferably from 10 to 300 μm. Inside the ink groove 43, an ejection electrode 22 b is provided. This ejection electrode 22 b may be provided throughout or only on a part of the inner surface of the ink groove 43 of the head body 40 comprising an insulating material, similarly to the case or the above-described apparatus, by a known method using an electrically conducting material such as aluminum, nickel, chromium, gold and platinum. The ejection electrodes are electrically isolated from each other. One cell is formed by two adjacent ink grooves and in the center thereof, a partition 44 is disposed. At the distal end of the partition, ejection parts 45, 45′ are provided. The partition is reduced in the thickness and sharpened at the ejection parts 45, 45′ as compared with other parts of the partition 44. Such a head body is manufactured using an insulating material block by a known method such as mechanical working, etching or molding. The thickness of the partition at the ejection part is preferably from 5 to 100 μm and the radius of curvature at the sharpened tip is preferably from 5 to 50 μm. The ejection part may be slightly chamfered as shown by 45′. In the Figures where only two cells are shown, the cells are divided by a partition 46 and the distal end 47 thereof is chambered to recede than the ejection parts 45, 45′. An ink is flown into this ejection head through the ink groove from the I direction by the ink feed member of the ink feed device (not shown) to feed the ink to the ejection part. The excess ink is recovered toward the O direction by ink recovery member (not shown), whereby a fresh ink is always fed to the ejection part. In this sate, when a voltage is applied to the ejection electrodes according to the image information, an ink is ejected from the ejection parts to the drum provided to oppose the ejection part and holding on the surface thereof a plate material and thereby an image is formed on the plate material.

[0195] Another example of the ejection head is described using FIG. 11. As shown in FIG. 11, the ejection head 22 has a pair of support members 50 and 50′ nearly in the rectangular shape. These support members 50 and 501 are formed of a plate-like material having an insulating property, such as plastic, glass or ceramic, and having a thickness of 1 to 10 mm. On one surface of each support member, a plurality of rectangular grooves 51, 51′ extending in parallel to each other are formed according to the recording resolution. Each groove 51, 51′ preferably has a width of 10 to 200 μm and a depth of 10 to 300 μm. Throughout or on a part of the inside thereof, an ejection electrode 22 is formed. By forming a plurality of grooves 51, 51′ on one surface of each support 50, 501 as such, a plurality of rectangular partitions 52 are necessarily provided between respective grooves 51. The support members 50 and 50′ are combined such that the surfaces having not provided thereon the grooves 51, 51′ face each other. Namely, the ejection head 22 has a plurality of grooves for passing an ink on the outer peripheral surface. The grooves 51 and 51′ formed on respective support members 50 and 50′ are connected through the rectangular part 54 of the ejection head 22 to correspond one by one. The rectangular parts 54 resultant from respective grooves being connected each recedes to a predetermined distance (from 50 to 500 μm) from the upper end 53 of the ejection head 22. In other words, the upper end 55 of each partition 52 in both sides of each rectangular part 54 of respective support members 50 and 50′ projects from the rectangular part 54. On each rectangular part 54, a guide projection 56 comprising an insulating material described above is provided to project therefrom, thereby forming an ejection part.

[0196] In the case of circulating an ink to the thus-constructed ejection head 22, an ink is fed to each rectangular part 54 through each groove 51 formed on the outer peripheral surface of one support member 50 and discharged through each groove 51′ formed on the support member 50′ in the opposite side. In this case, the ejection head 22 is inclined at a predetermined angle so as to enable smooth flow of the ink. That is, the ejection head 22 is inclined such that the ink feed side (support member 50) is positioned upward and the ink discharge side (support member 50′) is positioned downward. When an ink is circulated to the ejection head 22, the ink passing through each rectangular part 54 comes to full wetting along each projection 56, and an ink meniscus is formed in the vicinity of the rectangular part 54 and the projection 56. In this state where ink meniscuses are formed independently from each other on respective rectangular parts 54, a voltage is applied to the ejection electrode 22 b based on the image information and thereby, an ink is ejected from the ejection part toward the drum (not shown) provided to oppose the ejection part and holding on the surface thereof a plate material, as a result, an image is formed on the plate material. Here, a cover covering the grooves may be provided on the outer circumferential surface of each support member 50, 50′ to form a piped ink passage on the outer circumferential surface of each support member 50, 50′ and thereby forcedly circulate the ink through this ink passage. In this case, the ejection head 22 needs not be inclined.

[0197] The ejection head 22 described above using FIGS. 5 to 11 may contain a maintenance device such as head cleaning member, if desired. For example, in the case where the dormant state continues or where a trouble is generated in the image quality, means such as wiping off of the ejection head tip with a material having flexibility, such as scrub, brush or cloth, circulation of only an ink solvent, feed of only an ink solvent, and suction of the ejection part while circulating the ink solvent, may be used and by using these means individually or in combination, good drawing state can be maintained. For preventing the solidification of the ink, it is effective to cool the head part and thereby suppress the evaporation of ink solvent. In the case where the contamination is more sticking, a method of enforcedly suctioning the ink from the ejection part, a method of enforcedly flowing an air, ink or ink solvent jet from the ink passage, or a method of applying an ultrasonic wave while dipping the head in an ink solvent is effective. These methods may be used individually or in combination.

[0198] The plate material (printing original plate) for use in the present invention is described below.

[0199] Examples of the printing original plate include metal plates such as a steel plate subjected to plating with aluminum or chromium, An aluminum plate subjected to graining or anodization and thereby favored with a surface having good water retentivity and high abrasion resistance is particularly preferred. Also, a plate material obtained by providing an image-receiving layer on a water-resistant support such as a paper imparted with water resistance, a plastic film or a plastic-laminated paper, may be used and this plate material is more inexpensive. The thickness of the plate material is suitably from 100 to 300 μm and the thickness of the image-receiving layer provided thereon is suitably from 5 to 30 μm.

[0200] The image-receiving layer used may be a hydrophilic layer comprising an inorganic pigment and a binder or a layer which can be rendered hydrophilic by a desensitization treatment.

[0201] Examples of the inorganic pigment which can be used in the hydrophilic image-receiving layer include clay, silica, calcium carbonate, zinc oxide, aluminum oxide and barium sulfate. Examples of the binder which can be used include hydrophilic binders such as polyvinyl alcohol, starch, carboxymethyl cellulose, hydroxyethyl cellulose, casein, gelatin, polyacrylates, polyvinylpyrrolidone and polymethyl ether-maleic anhydride copolymers. If desired, a melamine-formalin resin, a urea-formalin resin or other cross-linking agent may also be added so as to impart water resistance.

[0202] Examples of the image-receiving layer which is used after a desensitization treatment include a layer using zinc oxide and a hydrophobic binder.

[0203] The zinc oxide used for use in the present invention may also be any commercial product available as zinc oxide, zinc white, wet zinc white or activated zinc white, which are described, for example, in Shinpan Ganryo Binran (Handbook of Pigments, New Edition), compiled by Nippon Ganryo Gijutsu Kyokai, issued by Seibundo, page 19 (1968).

[0204] That is, the zinc oxide includes those called a dry process such as French process (indirect process) and American process (direct process), and a wet process, according to the starting materials and the manufacturing method. Examples thereof include commercial products available from Seido Chemical Industry Co., Ltd., Sakai Chemical Industry Co., Ltd., Hakusui Chemical Industries, Ltd., The Honjo Chemical Corporation, Toho Zinc Co., Ltd., Mitsui Mining and Smelting Co., Ltd., and the like.

[0205] Specific examples of the resin used as a binder include styrene copolymers, methacrylate copolymers, acrylate copolymers, vinyl acetate copolymers, polyvinyl butyral, alkyd resins, epoxy resins, epoxy ester resins, polyester resins and polyurethane resins. These resins may be used individually or in combination of two or more thereof.

[0206] The content of the resin in the image-receiving layer is preferably, in terms of the weight ratio of resin/zinc oxide, from 9/91 to 20/80 by weight.

[0207] The desensitization of zinc oxide is performed by an ordinary method using a desensitizing solution and examples of conventionally known desensitizing solutions include a treating solution mainly comprising a ferrocyanate or a ferricyanate, a treating solution mainly comprising an ammine cobalt complex, a phytic acid or a derivative thereof, or a quanidine derivative, a treating solution mainly comprising an inorganic or organic acid capable of forming a chelate with zinc ion, and a treating solution containing a water-soluble polymer.

[0208] Examples of the treating solution containing a ferrocyanate include those described in JP-B-44-9045, JP-B-46-39403, JP-A-52-76101, JP-A-57-107889 and JP-A-54-117201.

[0209] The surface opposite the image-receiving layer of the plate material preferably has a Beck smoothness of 150 to 700 (sec/10 ml). With this smoothness, the produced printing plate can be free of occurrence of slipping or sliding on the plate cylinder during the printing and good printing can be attained.

[0210] The Beck smoothness can be measured by a Beck smoothness tester. The beck smoothness tester is a tester where a test piece is pressed on a circular glass plate finished to a high smoothness and having a hole in the center under a constant pressure (1 kgf/cm² (9.8 N/cm²)) and the time necessary for a constant amount (10 ml) of air passing through between the glass surface and the test piece under reduced pressure is measured.

[0211] The oil-based ink for use in the present invention is described below.

[0212] The oil-based ink for use in the present invention is obtained by dispersing resin particles which are solid at least at an ordinary temperature and are hydrophobic, in a nonaqueous solvent having an electric resistivity of 10⁹ Ωcm or more and a dielectric constant of 3.5 or less. The nonaqueous solvent having an electric resistivity of 10⁹ Ωcm or more and a dielectric constant of 3.5 or less for use in the present invention is preferably a linear or branched aliphatic hydrocarbon, an alicyclic hydrocarbon, an aromatic hydrocarbon or a halogen substitution product of these hydrocarbons. Examples thereof include hexane, heptane, octane, isooctane, decane, isodecane, decalin, nonane, dodecane, isododecane, cyclohexane, cyclooctane, cyclodecane, benzene, toluene, xylene, mesitylene, Isoper C, Isoper E, Isoper G, Isoper H, Isoper L (Isoper: a trade name of Exxon Corp.), Shellsol 70, Shellsol 71 (Shellsol: a trade name of Shell Oil Corp.), Amsco OMS solvent, Amsco 460 solvent (Amsco: a trade name of American Mineral Spirits Co.), and silicone oil. These are used individually or in combination. The upper limit of the electric resistivity of the nonaqueous solvent is about 10¹⁶ Ωcm and the lower limit of the dielectric constant is about 1.9. This nonaqueous solvent is also used as a cleaning solution by itself or in combination with another solvent.

[0213] The electric resistance of the nonaqueous solvent is specified to the above-described range because it the electric resistance is less than this range, resin particles or the like are not easily concentrated and a sufficiently long press life cannot be obtained. The dielectric constant is specified to the above-described range because if the dielectric constant exceeds this range, the electric field is relaxed due to polarization of the solvent and thereby, the ink is poorly ejected.

[0214] The resin particle dispersed in the nonaqueous solvent may be sufficient if it is a hydrophobic resin particle which is solid at a temperature of 35° C. or less and has high affinity for the nonaqueous solvent. However, the resin particle is preferably a resin (P) having a glass transition point of −5 to 110° C. or a softening point of 33 to 140° C., more preferably having a glass transition point of 10 to 100° C. or a softening point of 38 to 120° C., still more preferably having a glass transition point of 15 to 80° C. or a softening point of 38 to 100° C.

[0215] By using a resin having such a glass transition point or a softening point, the affinity between the surface of the image-receiving layer of the printing original plate and the resin particle increases and the bonding among resin particles is intensified on the printing original plate, so that the adhesion between the image area and the image-receiving layer is improved and the press life is also improved. If the glass transition point or softening point is lower or higher than the above-described range, the affinity between the surface of the image-receiving layer and the resin particle or the bonding force among resin particles may decrease.

[0216] The weight average molecular weight (Mw) of the resin (P) is from 1×10³ to 1×10⁶, preferably from 5×10³ to 8×10⁵, more preferably from 1×10⁴ to 5×10⁵.

[0217] Specific examples of the resin (P) include olefin polymers and copolymers (for example, polyethylene, polypropylene, polyisobutylene, ethylene-vinyl acetate copolymer, ethylene-acrylate copolymer, ethylene-methacrylate copolymer and ethylene-methacrylic acid copolymer), vinyl chloride polymers and copolymers (for example, polyvinyl chloride and vinyl chloride-vinyl acetate copolymer), vinylidene chloride copolymers, vinyl alkanoate polymers and copolymers, allyl alkanoate polymers and copolymers, polymers and copolymers of styrene and derivatives thereof (for example, butadiene-styrene copolymer, isoprene-styrene copolymer, styrene-methacrylate copolymer and styrene-acrylate copolymer), acrylonitrile copolymers, methacrylonitrile copolymers, alkyl vinyl ether copolymers, acrylic acid ester polymers and copolymers, methacrylic acid ester polymers and copolymers, itaconic acid diester polymers and copolymers, maleic acid anhydride copolymers, acrylamide copolymers, methacrylamide copolymers, phenolic resins, alkyd resins, polycarbonate resins, ketone resins, polyester resins, silicon resins, amide resins, hydroxyl group- or carboxyl group-modified polyester resins, butyral resins, polyvinyl acetal resins, urethane resins, rosin-type resins, hydrogenated rosin resins, petroleum resins, hydrogenated petroleum resins, maleic acid resins, terpene resins, hydrogenated terpene resins, chroman-indene resins, cyclic rubber-methacrylic acid ester copolymers, cyclic rubber-acrylic acid ester copolymers, copolymers containing a heterocyclic ring having no nitrogen atom (examples of the heterocyclic ring include furan ring, tetrahydrofuran ring, thiophene ring, dioxane ring, dioxofuran ring, lactone ring, benzofuran ring, benzothiophene ring and 1,3-dioxetane ring), and epoxy resins.

[0218] The content of resin particles dispersed in the oil-based ink for use in the present invention is preferably from 0.5 to 20 wt % based on the entire ink. If the content is less than this range, problems are liable to arise, for example, the ink can hardly have affinity for the surface of the printing original plate to fail in obtaining a good image or the press life is shortened. On the other hand, if the content exceeds the above-described range, uniform dispersion may not be easily obtained or non-uniform ink flow readily occurs in the ejection head to fail in attaining stable ink ejection.

[0219] The oil-based ink for use in the present invention preferably contains, together with the dispersed resin particles, a coloring material as a coloration component so as to facilitate inspection of the printing plate after the plate-making.

[0220] The coloring material may be any coloring material as long as it is a pigment or a dye conventionally used in oil-based ink compositions or liquid developers for electrostatic photography.

[0221] The pigment may be a pigment commonly used in the field of printing irrespective of an inorganic pigment or an organic pigment. Specific examples thereof include carbon black, cadmium red, molybdenum red, chrome yellow, cadmium yellow, titanium yellow, chromium oxide, viridian, cobalt green, ultramarine blue, Prussian blue, cobalt blue, azo-type pigments, phthalocyanine-type pigments, quinacridone-type pigments, isoindolinone-type pigments, dioxazine-type pigments, threne-type pigments, perylene-type pigments, perinone-type pigments, thioindigo-type pigments, quinophthalone-type pigments and metal complex pigments. These known pigments can be used without any particular limitation.

[0222] The dye is preferably an oil-soluble dye such as azo dye, metal complex salt dye, naphthol dye, anthraquinone dye, indigo dye, carbonium dye, quinoneimine dye, xanthene dye, aniline dye, quinoline dye, nitro dye, nitroso dye, benzoquinone dye, naphthoquinone dye, phthalocyanine dye and metallo-phthalocyanine dye.

[0223] These pigments and dyes may be used individually or in an appropriate combination. The coloring material is preferably contained in an amount of 0.01 to 5 wt % based on the entire ink.

[0224] The coloring material may be dispersed by itself as dispersed particles in the nonaqueous solvent separately from the dispersed resin particles or may be incorporated into the dispersed resin particles. In the latter case, a pigment may be generally incorporated by a method of covering the pigment with the resin material of the dispersed resin particle to form a resin-covered particle and a dye is generally incorporated by a method of coloring the surface area of the dispersed resin particle to form a colored particle.

[0225] In the present invention, the resin particles including the colored particles dispersed in the nonaqueous solvent preferably have an average particle size of 0.05 to 5 μm, more preferably from 0.1 to 1.0 μm. This particle size is determined by CAPA-500 (trade name, manufactured by Horiba Seisakusho Co., Ltd.).

[0226] The nonaqueous dispersed resin particle for use in the present invention may be produced by a conventionally known mechanical grinding method or polymerization granulating method. Examples of the mechanical grinding method include a method where materials for forming resin particles are mixed, if desired, and through melting and kneading, directly ground into fine particles by a known grinder and the fine particles are dispersed using a dispersion polymer in combination by a wet dispersing machine (for example, ball mill, paint shaker, Kedy mill or Dyno mill), and a method where materials for forming resin particles and a dispersion aid polymer (or covering polymer) are previously kneaded and the kneaded product is ground and then dispersed in the presence of a dispersion polymer. Specifically, a production process of coating materials or liquid developers for electrostatic photography may be utilized and this is described, for example, in Kenji Ueki (supervisor of translation), Toryo no Ryudo to Ganryou Bunsan (Flow of Coating Materials and Dispersion of Pigments), Kyoritsu Shuppan (1971), Solomon, Toryo no Kagaku (Science of Coatings), Hirokawa Shoten (1969), Yuji Harasaki, Coating Kogaku (Coating Engineering), Asakura Shoten (1971), and Yuji Harasaki, Coating no Kiso Kagaku (Basic Science of Coating), Maki Shoten (1977).

[0227] Examples of the polymerization granulating method include a conventionally known nonaqueous dispersion polymerization method and this is specifically described in publications such as Soichi Muroi (supervisor of compilation), Cho-Birvushi Polymer no Saishin Gijutsu (Latest Technology of Ultrafine Polymers), Chapter 2, CMC Shuppan (1991), Koichi Nakamura, Saikin no Denshi-Shasin Genzo System to Toner Zairyo no Kaihatsu/Jitsuyoka (Recent Electrophotographic Developing Systems and Development and Practical Use of Toner Materials), Chapter 3, Nippon Kagaku Joho Co., Ltd. (1985), and K. E. J. Barrett, Dispersion Polymerization in Organic Media, John Wiley (1975).

[0228] In order to dispersion-stabilizing the dispersed particles in the nonaqueous solvent, a dispersion polymer is usually used in combination. The dispersion polymer mainly comprises a repeating unit soluble in the nonaqueous solvent and preferably has an average molecular weight, in terms of a weight average molecular weight (Mw), of 1×10³ to 1×10⁶, more preferably from 5×10³ to 5×10⁵.

[0229] The preferred soluble repeating unit of the dispersion polymer for use in the present invention includes a polymerization component represented by the following formula (I):

[0230] wherein X₁ represents —COO—, —OCO— or —O—, R represents an alkyl or alkenyl group having from 10 to 32 carbon atoms, preferably an alkyl or alkenyl group having from 10 to 22 carbon atoms (the alkyl or alkenyl group may be linear or branched and may have a substituent but the alkyl or alkenyl group is preferably unsubstituted; specific examples thereof include a decyl group, a dodecyl group, a tridecyl group, a tetradecyl group, a hexadecyl group, an octadecyl group, an eicosanyl group, a docosanyl group, a decenyl group, a dodecenyl group, a tridecenyl group, a hexadecenyl group, an octadecenyl group and a linolenyl group), and a₁ and a₂, which may be the same or different, each represents a hydrogen atom, a halogen atom (e.g., chlorine, bromine), a cyano group, an alkyl group having from 1 to 3 carbon atoms (e.g., methyl, ethyl, propyl), —COO—Z₁ or —CH₂COO—Z₁ (wherein Z₁ represents a hydrocarbon group having 22 or less carbon atoms, which may be substituted, such as alkyl group, alkenyl group, aralkyl group, alicyclic group and aryl group).

[0231] Among the hydrocarbon groups represented by Z₁, preferred hydrocarbon groups are an alkyl group having from 1 to 22 carbon atoms, which may be substituted, such as methyl group, ethyl group, propyl group, butyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, dodecyl group, tridecyl group, tetradecyl group, hexadecyl group, octadecyl group, eicosanyl group, docosanyl group, 2-chloroethyl group, 2-bromoethyl group, 2-cyanoethyl group, 2-methoxycarbonylethyl group, 2-methoxyethyl group and 3-bromopropyl group; an alkenyl group having from 4 to 18 carbon atoms, which may be substituted, such as 2-methyl-1-propenyl group, 2-butenyl group, 2-pentenyl group, 3-methyl-2-pentenyl group, 1-pentenyl group, 1-hexenyl group, 2-hexenyl group, 4-methyl-2-hexenyl group, decenyl group, dodecenyl group, tridecenyl group, hexadecenyl group, octadecenyl group and linolenyl group; an aralkyl group having from 7 to 12 carbon atoms, which may be substituted, such as benzyl group, phenethyl group, 3-phenylpropyl group, naphthylmethyl group, 2-naphthylethyl group, chlorobenzyl group, bromobenzyl group, methylbenzyl group, ethylbenzyl group, methoxybenzyl group, dimethylbenzyl group and dimethoxybenzyl group: an alicyclic group having from 5 to 8 carbon atoms, which may be substituted, such as cyclohexyl group, 2-cyclohexylethyl group and 2-cyclopentylethyl group; and an aromatic group having from 6 to 12 carbon atoms, which may be substituted, such as phenyl group, naphthyl group, tolyl group, xylyl group, propylphenyl group, butylphenyl group, octylphenyl group, dodecylphenyl group, methoxyphenyl group, ethoxyphenyl group, butoxyphenyl group, decyloxyphenyl group, chlorophenyl group, dichlorophenyl group, bromophenyl group, cyanophenyl group, acetylphenyl group, methoxycarbonylphenyl group, ethoxycarbonylphonyl group, butoxycarbonylphenyl group, acetamidophenyl group, propionamidophenyl group and dodecyloylamidophenyl group.

[0232] The dispersion polymer may contain another repeating unit as a copolymerization component together with the repeating unit represented by formula (I). The another copolymerization component may be any compound as long as it comprises a monomer copolymerizable with the monomer corresponding to the repeating unit represented by formula (I).

[0233] The occupation percentage of the polymer component represented by formula (I) in the dispersion polymer is preferably 50 wt % or more, more preferably 60 wt % or more.

[0234] Specific examples of the dispersion polymer include those described in JP-A-10-204354, JP-A-10-204356, JP-A-10-259336, JP-A-10-306244, JP-A-10-316917 and JP-A-10-316920, and Resin (Q-1) for dispersion stabilization used in Examples. Also, commercially available products (for example, Solprene 1205, produced by Asahi Chemical Industry Co., Ltd.) may be used.

[0235] In the case of producing the particles of Resin (P) as a dispersion (latex) or the like, the dispersion polymer is preferably added in advance to the polymerization.

[0236] The amount added of the dispersion polymer is approximately from 1 to 50 wt % based on Resin (P) for particles.

[0237] The dispersed resin particle and colored particle (or coloring material particle) in the oil-based ink for use in the present invention each is preferably an electroscopic particle bearing positive or negative charge.

[0238] The electroscopicity can be imparted to these particles by appropriately using a technique of developers for wet electrostatic photography. To speak specifically, the electroscopicity is imparted using an electroscopic material such as charge controlling agent, and other additives described, for example, in Saikin no Denshi-Shasin Genzo System to Toner Zairyo no Kaihatsu/Jitsuyoka (Recent Electrophotographic Developing Systems and Development and Practical Use of Toner Materials), supra, pp. 139-148, Denshi Shashin Gijutsu no Kiso to Oyo (Elementary Study and Application of Electrophotographic Technology), Denshi Shashin Gakkai (compiler), pp. 497-505, Corona Sha (1988), and Yuji Harasaki, Denshi Shashin (Electrophotography), 16 (No. 2), page 44 (1977).

[0239] This is more specifically described, for example, in British Patents 893,429, 934,038 and 1,122,397, U.S. Pat. Nos. 3,900,412 and 4,606,989, JP-A-60-179751, JP-A-60-185963 and JP-A-2-13965.

[0240] The amount of such a charge controlling agent is preferably from 0.001 to 1.0 part by weight per 1,000 parts by weight of the dispersion medium as a carrier liquid. If desired, various additives may be further added and the upper limit of the total amount of these additives is determined by the electric resistance of the oil-based ink. More specifically, if the electric resistivity of the ink in the state where dispersed particles are removed is less than 10⁹ Ωcm, an image with good continuous gradation may not be obtained. Therefore, the amounts of the additives are preferably controlled within this limit.

[0241] A filter (filter material) 60 for use in the filtering of the present invention is described below using FIGS. 12 to 16. FIG. 12 is a view for explaining pores of the filter 60, FIG. 13 is a perspective view of a multilayer-type filter, FIG. 14 is a sectional view of a single plate-type filter, FIG. 15 is a sectional view of a tea strainer-type filter and FIG. 16 is an explanatory view of a coming back-type filter.

[0242] For the filter 60, a stainless steel-made wire-mesh filter material is predominantly used but other than this, construction materials such as paper, plastic (polymer, monomer), metal (SuS, copper) and ceramic are used. The pores for filtration of the filter material have a pore size of about 2 μm to thousands of μm in many cases but various filter materials as shown in FIG. 12 may be used, for example, a membrane filter of the type shown in FIG. 12(a) where pores having a uniform pore size are continued, a filter of the type shown in FIG. 12(b) where pores are different in the size and shape, or a filter of the type where the pore size is constantly reduced in sequence (not shown). The minimum distance of the pore is 2 μm or more, preferably 5 μm or more, as shown in FIG. 12(b). With respect to the kind of the filter material, a mesh-type filter material, a sintered metal-type filter material, a hollow yarn-type filter material and the like may be used.

[0243] With respect to the pore shape, a filter may be constructed such that the pore size is sequentially reduced as in the multilayer type shown in FIG. 13, which is obtained by staking a filter layer having coarse pores and a filter layer having dense pores. The filter of FIG. 13 is constructed to have a structure such that a coarse filter material layer having a large pore size and a dense filter material layer having a small pore size are stacked and a coarse mesh-type protective layer and a coarse mesh-type support layer are provided on the top and bottom thereof, respectively, to sandwich the filter layers. In this case, the filter material is a non-woven metal filter obtained by stacking and then sintering felts of stainless steel (SUS 316L) metal fiber and housed in a cylindrical case. The filter material has a thickness on the order of 0.09 to 0.65 mm and a pore size on the order of 3 to 60 μm.

[0244] With respect to the shape of the filter material, a multilayer cylinder-type filter (see, FIG. 13), a single plate-type filter having only one filter material layer (see FIG. 14) a cylinder-type filter obtained by bundling hollow yarns having micropores punched to provide a hollow state and thereby forming a hollow yarn film, which is used as a water-purifying filter or a filter element for pure water, and a so-called inline T-type tea strainer-type filter where, as shown in FIG. 15, a fluid (ink) flows from the outside to the inside of a filter element (e.g., SUS, A1), may be used. The inline T-type tea strainer-type filter which can be used includes an exchange-type (cartridge type) filter capable of easily removing only the filter element by unfastening the nut in the lower side and cleaning it, and a coming back-type filter shown in FIG. 16, which is used for sewage treatment and the like and in which filtering is repeated in sequence in respective chambers A, B, C, D . . . . This coming back-type filter has chambers A, B, C, D . . . , each having a filter function and when a contaminated solution enters into a fixture arm, the solution passes through the fixture arm to flow into a chamber A, the contaminated solution flown into the chamber A is filtered through a filter, the filtered solution flows out downward from the chamber A, and the sludge is accumulated in the chamber A. When the filter in the chamber A is clogged, the contaminated solution then flows into the adjacent chamber B and filtered in the chamber B. The filtered solution flows out downward from the chamber B and the sludge is accumulated in the chamber B. When the filter in the chamber B is clogged, the contaminated solution then flows into the adjacent chamber C and thereafter, the filtering is repeated in sequence. In this case, the clogged filters in the chambers A and B are not completely clogged and each chamber still functions as a precipitator. By virtue of these operations, the coming back filter is ensured with a long life and an excellent filtering activity. As such, the tea strainer-type filter is characterized in that the filter material itself can be taken out from the housing and exchanged, the hollow yarn-type filter is constructed such that the filter can be exchanged every each cartridge, and filters of other types can also be constructed that the filter can be exchanged every each cartridge based on the use time, the number of sheets drawn or the like.

[0245] With respect to the countermeasure for clogging of the filter 60, when deposits such es aggregate or dust is accumulated on the filter material such as a mesh, a removing treatment is appropriately performed using removal means such as ultrasonic irradiation, vibration or block flow of ink or cleaning solution. The removal timing may be controlled to automatically perform the removal at constant time intervals (e.g., use time, number of sheets drawn) or the removal may be appropriately performed by hand. In the ultrasonic irradiation, stirring member may also be used.

[0246] With respect to the filtering system using the filter material described above, the filtration is performed using the following systems individually or in combination, namely, a gravity filtration system of performing the filtration using the gravity of the stock solution (ink) passing through the filter material, a pressure filtration system of filtering ink while pressurizing it by means of a pump, a vacuum filtration system of sucking ink by means of a vacuum pump, and a constant rate filtration system of keeping the ink flow rate constant. The filtering system may be selected from these systems according to the conditions such as the position disposed (for example, immediately before the ejection head or after the pump), the form whether single plate-type or multilayer-type, and the performance.

[0247] The computer-to-cylinder type lithographic printing apparatus for use in practicing the lithographic printing process of the present invention is described below by referring to one construction example thereof.

[0248]FIG. 17 is an entire constructional view of a computer-to-cylinder type one-color one-side lithographic printing apparatus.

[0249] The printing process according to the present invention is described below using the entire constructional view of a computer-to-cylinder one-color one-side lithographic printing apparatus shown in FIG. 17. As shown in FIG. 17, the computer-to-cylinder type lithographic printing apparatus 1′ (hereinafter sometimes simply referred to as a “printing apparatus”) has one plate cylinders 11, one blanket cylinder 12 and one impression cylinder 13. These cylinders are disposed such that at least at the time of performing lithographic printing, the blanket cylinder 12 for transfer is pressed to come into contact with the plate cylinder 11′ and an impression cylinder 13 is pressed to come into contact with the blanket cylinder 12 for transferring the printing ink image transferred thereon to a printing paper P.

[0250] The plate cylinder 11′ is usually made of a metal and the surface thereof is subjected to, for example, chromium plating so as to intensify the abrasion resistance but the plate cylinder may have a heat insulating material on the surface thereof as described later. The plate cylinder 11′ acts as a counter electrode of the ejection head electrode at the electrostatic ejection and therefore, is preferably earthed. In the case where the substrate of the plate material has high insulating property, an electrically conducting layer is preferably provided on the substrate and in this case, means for taking the earth from this electrically conducting layer is preferably provided. In the case of providing a heat insulating material on the plate cylinder, the drawing may be facilitated also by providing means for taking earth from the plate material. In this case, known means having electrical conductivity, such as brush, leaf spring or roller may be used.

[0251] The printing apparatus 1′ further has an ink jet recording device (ink jet drawing device) 2 which ejects an oil-based ink on the plate material 9 mounted onto the plate cylinder 11′ in correspondence to the image data sent from an image data arithmetic and control part 21 and forms an image.

[0252] In the printing apparatus 1′, a fountain solution feed device 3 of feeding a fountain solution to the hydrophilic part (non-image area) on the plate material 9 is provided. FIG. 17 shows an apparatus using a Morton water feed system which is a representative example of the fountain solution feed device 3, however, other known devices such as SHINFLO water feed system and continuous water teed system may be used for the fountain solution feed device 3.

[0253] The printing apparatus 1′ further has a printing ink feed device 4 and a fixing device 5 for strengthening the oil-based ink image drawn on the plate material 9. If desired, a plate surface desensitizing device 6 may be provided for intensifying the hydrophilicity on the surface of the plate material 9.

[0254] The printing apparatus 1′ further has plate material surface dust-removing member 10 of removing dusts present on the surface of the plate material before and/or during the drawing on the plate material. By this means, the ink can be effectively prevented from adhering to the plate material by the help of dusts invaded between the head and the plate material during the plate-making and thereby, good plate-making can be attained. For the dust-removing member, a known non-contact method such as suction removal, blowing removal or electrostatic removal, or a contact method by a brush, a roller or the like may be used. In the present invention, air suction, air blowing or a combination thereof is preferably used. In this case, an air pump usually used in a paper feed device can be used to this purpose.

[0255] In addition, an automatic plate feed device 7 of automatically feeding a plate material 9 to be used in printing, onto the plate cylinder 11′ and an automatic plate discharge device 8 of automatically removing the plate material 9 from the plate cylinder 11′ after the completion of printing may be provided. Examples of the printing machine having these devices known as auxiliary devices of a printing machine include Hamada VS34A, B452A (manufactured by Hamada Insatsu Kikai K.K.), TOKOH 8000PFA (manufactured by Tokyo Koku Keiki K.K.), Ryobi 3200ACD, 3200PFA (manufactured by Ryobi Imagisk K.K.), AMSIS Multi5150FA (manufactured by Nippon AM K.K.), Oliver 266 EPZ (manufactured by Sakurai Graphic Systems K.K.) and Shinohara 66IV/IVP (manufactured by Shinohara Shoji K-K.). Furthermore, a blanket cleaning device 14 and an impression cleaning device 14′ may also be provided. By using these devices 7, 8, 14 and 14′, the printing operation is more facilitated and the printing time can be shortened, as a result, the effect of the present invention can be more elevated. In the vicinity of the impression cylinder 13, a paper dust generation-preventing device (paper dust-removing member) 15 may be provided so as to prevent paper dusts from adhering to the plate material. The paper dust generation-preventing device 15 may employ humidity control, suction by air or electrostatic force, or the like.

[0256] The image data arithmetic and control part 21 receives image data from an image scanner, a magnetic disc device, an image data transmission device or the like, performs color separation and at the same time, partitions and computes the separated data into an appropriate number of picture elements or an appropriate number of gradations. Furthermore, since the oil-based ink image is drawn as a dotted image using an ink jet ejection head 22 (see, FIG. 3; this is described in detail later) as an ejection head of the ink jet recording device 2, the halftone dot area factor is also computed.

[0257] In addition, as described layer, the image data arithmetic and control part 21 controls the movement of the ink jet ejection head 22, the timing of ejecting the oil-based ink and if desired, the timing of operating the plate cylinder 11′, the blanket cylinder 12, the impression cylinder 13 and the like.

[0258] The process of preparing a printing plate by the printing apparatus 1′ is described below by referring to FIG. 18 and partially to FIG. 3.

[0259] A plate material 9 is mounted onto the plate cylinder 11′ using an automatic plate feed device 7. At this time, the plate material is tightly fixed on the plate cylinder by a mechanical method using a known plate head/edge gripping device, an air suction device or the like, or by an electrostatic method, so that the edge of plate can be prevented from fluttering to come into contact with the ink jet recording device 2 during the drawing and cause damages. Furthermore, means of tightly contacting the plate material to the plate cylinder only in the periphery of the drawing position of the ink jet recording device may be provided and by actuating this at least at the time of performing the drawing, the plate material can also be prevented from contacting with the ink jet recording device. To speak specifically, for example, a method of disposing a presser roller upstream and downstream the drawing position of the plate cylinder may be used.

[0260] Also, means of preventing the plate edge from contacting with an ink feed roller during the process of fixing the plate may be provided and thereby, the staining of the plate surface can be prevented and the loss paper can be reduced. Specifically, a presser roller, a guide or electrostatic adsorption is effective.

[0261] The image data from a magnetic disk device or the like is given to an image data arithmetic and control part 21 and according to the input image data, the image data arithmetic and control part 21 computes the position of ejecting an oil-based ink and the halftone dot area factor at that position. These computed data are once stored in a buffer. The image data arithmetic and control part 21 rotates the plate cylinder 11′ and approximates the ejection head 22 to the position proximate to the plate cylinder 11′ using a head-retreating/approximating device (ejection head-retreating/approximating member) 31. The ejection head 22 and the surface of the plate material 9 on the plate cylinder 11′ are kept at a predetermined distance during the drawing using mechanical distance controlling member such as knock roller or under the control of the head-retreating/approximating device based on the signals from an optical distance detector. By this distance control, good plate-making can be attained without causing non-uniformity in the dot size due to floating of the plate material or particularly without causing any change in the dot size even when vibration is applied to the printing machine.

[0262] For the ejection head 22, a single channel head, a multi-channel head or a full line head may be used and the main scanning is performed by the rotation of the plate cylinder 11′. In the case of a multi-channel head having a plurality of ejection parts or a full line head, the array direction of ejection parts is set to the axial direction of the plate cylinder. Furthermore, in the case of a single channel head or a multi-channel head, the head 22 is moved in the direction parallel to the axis of the plate cylinder by the image data arithmetic and control part 21 every each rotation of the plate cylinder 11′ and an oil-based ink is ejected to the plate material 9 mounted onto the plate cylinder 11′ at the ejection position and at the halftone dot area factor obtained by the computation. By this ejection, a halftone image is drawn on the plate material 9 by the oil-based ink according to the variable density of the printing original. This operation continues until an oil-based ink image of one color portion of the printing original is formed on the plate material 9 and a printing plate is finished.

[0263] On the other hand, in the case where the ejection head 22 is a full line head having almost the same length as the width of the plate cylinder, an oil-based ink image of one color portion of the printing original is formed on the plate material 9 by one rotation of the plate cylinder and thereby a printing plate is finished. As such, the main scanning is performed by the rotation of the plate cylinder and therefore, the positional precision in the main scanning direction can be elevated and high-speed drawing can be performed.

[0264] The ejection head 22 is then retreated to come apart from the position proximate to the plate cylinder 11′ so as to protect the ejection head 22. At this timer only the ejection head 22 may be retreated but the ejection head and the head sub scanning means 32 together or the ejection head 22, the ink feed part 24 and the head sub scanning means 32 all may be retreated. Together with ejection head 22, the ink feed part 24 and the head sub scanning means 32, the fixing apparatus 5 and the dust-removing member 10 each may also be made capable of retreating by providing a retreating/approximating member and thereby, normal printing can be performed.

[0265] This retreating/approximating member is operated to separate the ejection head at least 500 μm or more apart from the plate cylinder except for the drawing time. The retreating/approximating operation may be performed by a slide system ox in a pendulum manner by fixing the head using an arm fixed to a certain axis and moving the arm around the axis. By retreating the head at the non-drawing time, the head can be protected from the physical breakage or contamination and can have a long life.

[0266] The oil-based ink image formed is intensified by heating in a fixing apparatus 5. For fixing the ink, known means such as heat-fixing, solvent fixing and flash exposure fixing may be used. In the heat-fixing, hot air fixing by the irradiation of an infrared lamp, a halogen lamp or a xenon flash lamp or using a heater, or heat-roller fixing is generally employed. In this case, the fixing property can be effectively elevated by using individually or in combination the means such as heating of plate cylinder, preheating of the plate material, drawing while applying hot air, coating of the plate cylinder with a heat insulating material, and heating of only the plate material by separating the plate material from the plate cylinder only at the fixing. The flash fixing using a xenon lamp or the like is known as a fixing method of electrophotographic toner and this is advantageous in that the fixing can be performed within a short time. In the solvent fixing, a solvent capable of dissolving the resin components in the ink, such as methanol or ethyl acetate, is sprayed and excess solvent vapor is recovered.

[0267] At least in the process from the formation of an oil-based ink image by the ejection head 22 until the fixing by the fixing apparatus 5, the fountain solution feed device 3, the printing ink feed device 4 and the blanket cylinder 12 are preferably kept not to come into contact with the plate material 9 on the plate cylinder.

[0268] The printing process after the formation of the printing plate is performed in the same manner as in a known lithographic printing process. More specifically, a printing ink and a fountain solution are given to the plate material 9 having drawn thereon an oil-based ink image to form a printing image, the printing ink image is transferred to a blanket cylinder 12 rotating together with the plate cylinder 11′ and subsequently, the printing ink image on the blanket cylinder 12 is transferred to a printing paper sheet P passing through between the blanket cylinder 12 and the impression cylinder 13, thereby performing printing of one color portion. After the completion of printing, the plate material 9 is removed from the plate cylinder 11′ by the automatic plate discharge device 8 and the blanket on the blanket cylinder 12 is cleaned by the blanket cleaning device 14 to provide a state where next printing can be performed.

[0269] The ink jet drawing device 2 used is as described above with respect to the plate-making apparatus.

[0270] In the computer-to-cylinder type lithographic printing apparatus, the image data arithmetic and control part 21 computes the input image data and moves the head 22 using a head-retreating/approximating device 31 or head sub-scanning means 32, as described above, and additionally takes in the timing pulse from an encoder 30 disposed in the plate cylinder and drives the head 22 according to the timing pulse. By this, the positional precision in the sub-scanning direction is elevated. The positional precision in the sub-scanning direction at the time of performing the drawing by the ink jet recording device can also be elevated by driving the plate cylinder using high-precision driving means different from the driving means used at the printing. In this case, the driving means is preferably mechanically separated from the blanket cylinder, the impression cylinder and others and drives only the plate cylinder. To speak more specifically, a method of reducing the output from, for example, a high-precision motor by a high-precision gear or a steel belt and driving only the plate cylinder may be used. In performing a high-quality drawing, these means are used individually or in combination.

[0271] The ejection head used is the same as described above with respect to the plate-making apparatus except that the drum 11 is replaced by a plate cylinder 11′.

[0272] A computer-to-cylinder type multicolor one-side lithographic printing apparatus, which is a specific example of the present invention, is described below.

[0273]FIG. 18 shows an entire construction example of a computer-to-cylinder type four-color one-side lithographic cut sheet printing apparatus. As shown in FIG. 18, the four-color one-side lithographic cut sheet printing apparatus fundamentally has a structure such that the plate cylinder 11′, the blanket cylinder 12 and impression cylinder 13 of a single color one-side printing apparatus each is disposed in four units and the printing is performed on the same surface of a printing paper sheet P. Although not shown in the figure, the delivery of the printing paper sheet between adjacent impression cylinders, shown by K in the figure, is performed using a known transfer cylinder system or the like. As easily understood from the example of FIG. 18, other multicolor one-side printing apparatuses fundamentally have a structure, though not described here in detail, such that the plate cylinder 11′, the blanket cylinder 12 and impression cylinder 13 of a single color one-side printing apparatus each is disposed in multiple units and the printing is performed on the same surface of a printing paper sheet P. In the case of manufacturing only one color portion plate on the plate cylinder, the plate cylinder and the blanket cylinder each is disposed in the number of units corresponding to the number of colors used for the printing (such a printing apparatus is called a unit-type printing apparatus). On the other hand, in the case of practicing the present invention by a common impression cylinder-type printing apparatus of commonly using one impression cylinder having a diameter as large as integral times the diameter of the plate cylinder while having the plate cylinder and the blanket cylinder each in the number of units corresponding to the multiple color portions, the printing apparatus may have a structure such that the plate cylinder and the blanket cylinder each in the number of units corresponding to the multiple color portions to be printed commonly use one impression cylinder or such that a plurality of structures of commonly using one impression cylinder by the plate cylinder and the blanket cylinder each in the number of units corresponding to multiple color portions are provided and the total number of each of the plate cylinder and the blanket cylinder corresponds to the number of colors printed. In this case, the delivery of the printing paper sheet between adjacent common impression cylinders may be performed by the above-described known transfer cylinder system.

[0274] In the case of manufacturing plates of multiple colors on a plate cylinder, the plate cylinder and the blanket cylinder each must be provided in the number of units corresponding to the value obtained by dividing the number of colors printed by the number of plates on one plate cylinder. For example, in the case of manufacturing plate materials of two color portions on a plate cylinder, one-side four-color printing can be attained by a printing apparatus having two plate cylinders and two blanket cylinders. In this case, the diameter of the impression cylinder is the same as the size of the plate cylinder of one color portion, means for holding a printing paper sheet until the completion of printing of necessary color portions is provided to the impression cylinder, if desired, and the delivery of the printing paper sheet between impression cylinders is performed using a known transfer cylinder system. In the case of the above-described apparatus having two plate cylinders having formed thereon plate materials of two color portions and having two blanket cylinders, one impression cylinder rotates twice while holding a printing paper sheet to perform two-color printing, the printing paper sheet is delivered between impression cylinders, and the other impression cylinder rotates twice while holding the printing paper sheet to perform two-color printing, thereby completing four-color printing. The number of impression cylinders may be the same as the number of plate cylinders but some plate cylinders and some blanket cylinders may commonly use on impression cylinder.

[0275] In the case of practicing the present invention as a computer-to-cylinder type multicolor two-side lithographic cut sheet printing apparatus, the printing apparatus has a structure such that known printing paper-reversing means is provided in at least one space between adjacent impression cylinders of the above-described unit-type printing apparatus, a structure such that a plurality of common impression cylinder-type printing apparatuses are disposed and known printing paper-reversing means is provided in at least one space between adjacent impression cylinders, or a structure such that the plate cylinder 11′ and the blanket cylinder 12 of a single color one-side printing apparatus shown in FIG. 17 are disposed in multiple units to perform the printing on both surfaces of the printing paper sheet P. In the structure shown in FIG. 17, when only a plate of one color portion is manufactured on the plate cylinder, the plate cylinder and the blanket cylinder are provided in the number of units corresponding to the number of colors necessary for the printing on both surfaces of a printing paper sheet. On the other hand, in the case of manufacturing plates of multiple colors on the plate cylinder as described above, the number of plate cylinders, the number of blanket cylinders and the number of impression cylinders can be reduced. In the case of commonly using one impression cylinder by some plate cylinders and some blanket cylinders, the number of impression cylinders can be more reduced. If desired, means of holding the printing paper sheet until the completion of printing of necessary color portions is provided on the impression cylinder. This can be easily understood from the above-described example of a computer-to-cylinder type multicolor one-side lithographic printing machine and therefore, is not described in detail here.

[0276] As such, an example of a cut sheet printing apparatus is described as a practical embodiment of the computer-to-cylinder type multicolor lithographic printing apparatus of the present invention. In the case of practicing the present invention as a computer-to-cylinder type multicolor WEB (rolled paper) lithographic printing apparatus, the above-described unit type and common impression cylinder type can be suitably used. Furthermore, in the case of practicing the present invention as a computer-to-cylinder type multicolor WEB two-side printing apparatus, this can be achieved in both the unit type and the common impression cylinder type by having a structure such that known WEB-reversing means is provided in at least one space between adjacent impression cylinders or a structure such that a plurality of such means are provided so as to perform the printing on both surface of the printing paper sheet P. The computer-to-cylinder type multicolor WEB two-side printing apparatus is most suitably a BB (blanket-to-blanket) type printing apparatus where a structure of having a plate cylinder of one color portion for performing the printing on one surface of WEB, a blanket cylinder (without impression cylinder), a plate cylinder of one color portion for performing the printing on another surface of WEB and another blanket cylinder (without impression cylinder) and press-contacting the blanket cylinders with each other at the printing, is provided in the number of units corresponding to the number of colors and the WEB is passed through between press-contacted blankets at the printing, thereby achieving multicolor two-side printing.

[0277] In another example of the computer-to-cylinder type lithographic printing apparatus, two plate cylinders are provided per one blanket cylinder and while performing the printing by one plate cylinder, the drawing may be performed on another plate cylinder. In this case, the driving of the plate cylinder under drawing is preferably made independent from the blanket by mechanical means. By constructing as such, the drawing can be performed without stopping the printing machine. Incidentally, as easily understood, this computer-to-cylinder type lithographic printing apparatus can be applied to the computer-to-cylinder type multicolor one-side lithographic printing apparatus or computer-to-cylinder type multicolor two-side lithographic printing apparatus.

[0278] The present invention will be described in greater detail by referring to the following Examples, but the invention should not be construed as being limited thereto.

[0279] A production example of Resin Particle (PL) for ink is described below.

PRODUCTION EXAMPLE 1 OF RESIN PARTICLE (PL-1):

[0280] A mixed solution containing 10 g of Resin (Q-1) for dispersion stabilization having a structure shown below, 100 g of vinyl acetate and 384 g of Isoper H was heated to a temperature of 70° C. while stirring in a nitrogen stream. Thereto, 0.8 g of 2,2′-azobis(isovaleronitrile) (hereinafter simply referred to as “A.I.V.N.”) was added as a polymerization initiator and reacted for 3 hours. 20 Minutes after the addition of the initiator, the solution turned to milky white and the reaction temperature was elevated to 88° C. Thereto, 0.5 g of the same initiator was further added and reacted for 2 hours. Thereafter, the temperature was elevated to 100° C., the reaction solution was stirred for 2 hours, and unreacted vinyl acetate was removed by distillation. The residue was cooled and passed through a 200-mesh nylon cloth. The white dispersion obtained was a latex having a polymerization percentage of 90%, an average particle size of 0.23 and good monodispersity. The particle size was measured by CAPA-500 (manufactured by Horiba Seisakusho K.K.).

[0281] Resin (Q-1) for Dispersion Stabilization:

[0282] Mw: 5×10⁴

[0283] A part of this white dispersion was centrifuged (revolution number: 1×10⁴ rpm, revolution time: 60 minutes) and the precipitated resin particle portion was collected and dried. The resin particle portion had a weight average molecular weight (Mw, GPC value in terms of polystyrene) of 2×10⁵ and a glass transition point (Tg) of 38° C.

EXAMPLE 1

[0284] An oil-based ink was prepared.

[0285] <Preparation of Oil-based Ink (IK-1)>

[0286] Into a paint shaker (manufactured by Toyo Seiki K.K.), 10 g of dodecyl methacrylate/acrylic acid copolymer (copolymerization ratio: 95/5 by weight), 10 g of nigrosine and 30 g of Shellsol 71 were charged together with glass beads and dispersed for 4 hours to obtain a fine nigrosine dispersion of nigrosine.

[0287] Then, 60 g (as solid contents) of Resin Particle (PL-1) produced in Preparation Example 1 of Resin Particle for Ink, 2.5 g of the nigrosine dispersion prepared above, 15 g of FOC-1400 (tetradecyl alcohol, produced by Nissan Chemical Industries Co., Ltd.) and 0.08 g of an octadecene-half maleic acid octadecylamide copolymer were diluted with 1 liter of Isoper G to prepare a black oil-based ink.

[0288] Thereafter, 2 liter of the thus-prepared oil-based ink (IK-1) was filled in an ink tank of an ink jet drawing device 2 of a plate-making apparatus (see, FIG. 1 and FIG. 3). The ejection head used here was a 900 dpi multi-channel head of 64 channels shown in FIG. 5 and a filter 60 was inserted into the ink inflow passage. In the ink tank, an immersion heater and a stirring blade were provided as the ink temperature-controlling member and by setting the ink temperature to 30° C., the temperature was controlled using a thermostat while rotating the stirring blade at 30 rpm. The stirring blade used here was also served as stirring member for preventing precipitation and coagulation. A part of the ink passage was made transparent, and an LED light-emitting device and a light-detecting device were disposed to sandwich the transparent portion. Based on the output signal therefrom, the concentration was controlled by charging a diluting solution (Isoper G) for ink or a concentrated ink (prepared by adjusting the solid concentration of Ink (IK-1) to 2 times).

[0289] A 0.12 mm-thick aluminum plate subjected to graining and anodization was used as the plate material and fixed to the drum of a plate-making apparatus by mechanical means provided on the drum while gripping the head and edge of the plate. After removing dusts on the surface of the plate material by suction using an air pump, the ejection head was approximated to the drawing position of the plate material. Then, the image data to be drawn were transmitted to the image data arithmetic and control part and the 64-channel ejection head was moved while rotating the drum, thereby ejecting an oil-based ink onto the aluminum plate to form an image. At this time, the tip width of the ejection electrode of the ink jet head was 10 μm and the distance between the head and the plate material was controlled to 1 mm by the output from an optical gap-detecting device. A voltage of 2.5 KV was always applied as a bias voltage and at the time of performing the ejection, a pulse voltage of 500 V was superimposed. The pulse voltage was changed through 256 stages in the range from 0.2 to 0.05 msec so as to perform the drawing while changing the dot area. As a result, good plate-making was attained, where drawing failure due to ink aggregate or dust was not observed at all and the image was completely free of deterioration due to change in the dot size or the like even when the number of processed plates increased.

[0290] The image was further firmly fixed by the heating using a xenon flash fixing apparatus (manufactured by Ushio Denki, emission intensity: 200 J/pulse), thereby manufacturing a printing plate. The ink jet drawing device with the sub-scanning means was retreated 50 mm from the position proximate to the drum so as to protect the ink jet head. Thereafter, the printing plate was taken out from the plate-making apparatus and mounted onto the plate cylinder of Oliver 266 EPZ printing apparatus and then, the printing was performed.

[0291] The printed matters obtained had a very clear image free of slipping or thinning of the printed image even after 10,000 sheets were continuously printed.

[0292] 10 Minutes after the completion of plate-making, Isoper G was fed to the head and the head was cleaned by dripping Isoper G from the head opening and then stored in a cover filled with a vapor of Isoper G, as a result, a printing plate capable of giving good printed matters could be obtained without requiring any maintenance operation for 3 months.

EXAMPLE 2

[0293] In an apparatus shown in FIG. 2, a 600 dpi full line ink jet head of the type shown in FIG. 7 was disposed. A pump was used for the circulation of ink and an ink reservoir was provided between this pump and the ink inflow passage of the ejection head and between the ink recovery passage of the ejection head and the ink tank. The ink was circulated using the difference in the hydrostatic pressure therebetween. A heater and the above-described pump were used as the ink temperature-controlling member and the ink temperature set to 35° C. was controlled by a thermostat. The circulation pump used here was served also as the stirring member for preventing the precipitation and coagulation. A filter 60 was disposed immediately before the ejection head and an electrical conductivity-measuring device was disposed on the ink passage. Based on the output signal therefrom, the ink concentration was controlled by diluting the ink or charging a concentrated ink. The aluminum plate prepared above was fixed as the plate material in the same manner to the drum of a plate-making apparatus. After removing dusts on the surface of the plate material using a nylon-made rotary brush, the image data to be drawn was transmitted to the image data arithmetic and control part and while transporting the plate material by capstan rollers, the full line head was allowed to perform the drawing by ejecting an oil-based ink onto the aluminum plate to form an image. As a result, good plate-making could be attained, where drawing failure and the like ascribable to ink aggregates or mingling of foreign matters such as dust were not observed at all and even when the ambient temperature was changed or the number of processed plates increased, the image was completely free from deterioration due to change in the dot size and the like. The image was firmly fixed by the heating (pressure: 3 kgf/cm² (29.4 N/cm²)) of heat roller (Teflon seal silicon rubber roller self-containing a halogen lamp of 300 W) fixing.

[0294] Using the plate manufactured, printing was performed in the same manner as in Example 1, as a result, a very clear image free of slipping or thinning of the printed image could be obtained even after 10,000 sheets were continuously printed. After the completion of plate-making, Isoper G was circulated to the head and then a non-woven fabric impregnated with Isoper G was contacted with the head tip to perform the cleaning, as a result, a printing plate capable of giving good printed matters could be manufactured without requiring any maintenance operation for 3 months.

[0295] Furthermore, the drawing and printing were performed in the same manner except for using a 600 dpi full line ink jet head of the type shown in FIG. 9 and FIG. 11 in place of the ink jet head of the type shown in FIG. 7, as a result, good results were obtained similarly to the above.

EXAMPLE 3

[0296] An operation was performed in the same manner as in Example 1 except that a plate material having provided on the surface thereof an image-receiving layer capable of hydrophilizing by a desensitization treatment, described below, was used in place of the aluminum plate of Example 1, the non-image area after the preparation of the printing plate was hydrophilized using a plate surface-desensitizing device, the electrically conducting layer of the plate material was earthed by the contact with an electrically conducting plate spring (made of phosphor bronze) at the time of drawing, and the fixing was performed by blowing hot air to the plate material.

[0297] A wood-free paper having a basis weight of 100 g/m² was used as the substrate. On both surfaces of the substrate, a polyethylene film was laminated to a thickness of 20 μm to render the surfaces water-resistant and on this paper support, a coating material for the electrically conducting layer prepared as follows to have a composition shown below was coated to have a dry coated amount of 10 g/m². Thereon, Dispersion Solution A was further coated to have a dry coated weight of 15 g/m², thereby providing an image-receiving layer. This was used as the plate material.

[0298] Coating Material for Electrically Conducting Layer:

[0299] 5.4 Parts of carbon black (30% water solution), 54.6 parts of clay (50% water solution), 36 parts of SBR latex (solid content: 50%, Tg: 25° C.) and 4 parts of melamine resin (Sumirez Resin SR-613, solid content: 80%) were mixed and water was added to make a total solid content of 25%, thereby preparing the coating material.

[0300] Dispersion Solution A:

[0301] A mixture containing 100 g of dry zinc oxide, 3 g of Binder Resin (B-1) having a structure shown below, 17 g of Binder Resin (B-2) having a structure shown below, 0.15 g of benzoic acid and 155 g of toluene was dispersed using a wet dispersing machine Homogenizer (manufactured by Nippon Seiki K.K.) at a revolution number of 6,000 rpm for 8 minutes.

[0302] Binder Resin (B-1)

[0303] Mw: 9×10³

[0304] Binder Resin (B-2)

[0305] (by weight)

[0306] Mw: 4×10⁴

[0307] At the time of performing the fixing by blowing hot air to the plate material, blister was generated. Accordingly, the fixing was performed by gradually and continuously elevating the supply power to the heater used for the blowing of hot hair or by gradually and continuously reducing the rotation speed of the drum from high sped to low speed while not changing the supply power. As a result, blister was not generated and the printed matter obtained by the printing using the thus-obtained printing plate had a very image tree of slipping or thinning of the printed image even after 5,000 sheets were continuously printed.

[0308] In Examples 1 to 3, when the drawing was performed without using the filter 60, the ejection became unstable within several hours to several days in any Example and after disorder of image or non-ejection state continued, the ejection port of the head was completely clogged by coarse semisolid aggregate of ink particles at the worst time and the drawing could not be performed.

EXAMPLE 4

[0309] 2 Liter of Oil-based ink (IK-1) prepared above was filled in an ink jet recording device of a computer-to-cylinder type lithographic printing apparatus (see, FIG. 17 and FIG. 3). The ejection head used here was a 900 dpi multi-channel head of 64 channels shown in FIG. 5 and a filter 60 was inserted into the ink inflow passage. In the ink tank, an immersion heater and a stirring blade were provided as the ink temperature-controlling member and by setting the ink temperature to 30° C., the temperature was controlled using a thermostat while rotating the stirring blade at 30 rpm. The stirring blade used here was also served as stirring member for preventing precipitation and coagulation. A part of the ink passage was made transparent, and an LED light-emitting device and a light-detecting device were disposed to sandwich the transparent portion. Based on the output signal therefrom, the concentration was controlled by charging a diluting solution (Isoper G) for ink or a concentrated ink (prepared by adjusting the solid concentration of Ink (IK-1) to 2 times).

[0310] A 0.12 mm-thick aluminum plate subjected to graining and anodization was used as the plate material and fixed to the plate cylinder by a mechanical device provided on the plate cylinder while gripping the head and edge of the plate. The fountain solution feed device, the printing ink feed device and the blanket cylinder were kept apart not to come into contact with the plate material and after removing dusts on the surface of the plate material by suction using an air pump, the ejection head was approximated to the drawing position of the plate material. Then, the image data to be printed were transmitted to the image data arithmetic and control part and the 64-channel ejection head was moved while rotating the plate cylinder, thereby ejecting an oil-based ink onto the aluminum plate to form an image. At this time, the tip width of the ejection electrode of the ink jet head was 10 μm and the distance between the head and the plate material was controlled to 1 mm at all times according to the output from an optical gap-detecting device. A voltage of 2.5 KV was always applied as a bias voltage and at the time of performing the ejection, a pulse voltage of 500 V was superimposed. The pulse voltage was changed through 256 stages in the range from 0.2 to 0.05 msec so as to perform the drawing while changing the dot area. As a result, good plate-making was attained, where drawing failure due to ink aggregate, mingled foreign matters such as solid dust, or powder dust was not observed at all and the image was completely free of deterioration due to change in the dot size or the like even when the ambient temperature was changed or the number of processed plates increased.

[0311] The image was further firmly fixed by the heating using a xenon flash fixing apparatus (manufactured by Ushio Denki, emission intensity: 200 J/pulse), thereby manufacturing a printing plate. The ink jet drawing device with the sub-scanning means was retreated 50 mm from the position proximate to the drum so as to protect the ink jet head. Thereafter, printing was performed on a coated paper for printing in the same manner as above by a normal lithographic printing process. That is, a printing ink and a fountain solution were given to form a printing image, this printing ink image was transferred onto a blanket cylinder rotating together with the plate cylinder and the printing ink image on the blanket cylinder was transferred to the coated paper for printing passing through between the blanket cylinder and the impression cylinder.

[0312] The printed matters obtained had a very clear image free of slipping or thinning of the printed image even after 10,000 sheets were continuously printed.

[0313] 10 Minutes after the completion of plate-making, Isoper G was fed to the head and the head was cleaned by dripping Isoper G from the head opening and then stored in a cover filled with a vapor of Isoper G, as a result, good printed matters could be obtained without requiring any maintenance operation for 3 months.

EXAMPLE 5

[0314] A circulation pump was used as the stirring member and a 600 dpi full line ink jet head of the type shown in FIG. 7 was disposed. A pump was used here and an ink reservoir was provided between this pump and the ink inflow passage of the ejection head and between the ink recovery passage of the ejection head and the ink tank. The ink was circulated using the difference in the hydrostatic pressure therebetween. A heater and the above-described pump were used as the ink temperature-controlling member and the ink temperature set to 35° C. was controlled by a thermostat. The circulation pump used here was served also as the stirring member for preventing the precipitation and coagulation. A filter 60 was disposed immediately before the ejection head and an electrical conductivity-measuring device was disposed on the ink passage. Based on the output signal therefrom, the ink concentration was controlled by diluting the ink or charging a concentrated ink. The aluminum plate described above was mounted as the plate material in the same manner to the plate cylinder of a lithographic printing apparatus, After removing dusts on the surface of the plate material using a nylon-made rotary brush, the image data to be printed was transmitted to the image data arithmetic and control part and while transporting the plate cylinder, the full line head was allowed to perform the drawing by ejecting an oil-based ink onto the aluminum plate to form an image. As a result, good plate-making could be attained, where drawing failure and the like ascribable to ink aggregates, mingled foreign matters such as solid dust, or powder dust were not observed at all and even when the ambient temperature was changed or the number of processed plates increased, the image was completely free from deterioration due to change in the dot size and the like and good plate-making could be performed. The image was firmly fixed by the heating using a heat roller fixing device (produced by Hitachi Kinzoku K.K., powder: 1.2 kW). This was used as the plate material.

[0315] Using the plate manufactured, printing was performed, as a result, a very clear image free of slipping or thinning of the printed image could be obtained even after 10,000 sheets were continuously printed. After the completion of plate-making, Isoper G was circulated to the head and then a non-woven fabric impregnated with Isoper G was contacted with the head tip to perform the cleaning, as a result, good printed matters could be obtained without requiring any maintenance operation for 3 months.

[0316] Furthermore, the drawing and printing were performed in the same manner except for using a 600 dpi full line ink jet head of the type shown in FIG. 9 and FIG. 11 in place of the ink jet head of the type shown in FIG. 7, as a result, good results were obtained similarly to the above.

EXAMPLE 6

[0317] A full line head shown in FIG. 9 was used as the ejection head for the ink jet recording device of a computer-to-cylinder type four-color one-side lithographic printing apparatus (see, FIG. 18) and the gap was adjusted (gap: 0.8 mm) by a Teflon-made knock roller. Thereafter, 5,000 plates were manufactured by performing the same operation as in Example 1 except for supplying a concentrated ink to the ink tank according to the number of drawn plates as the ink concentration-controlling member. As a result, drawing failure due to ink aggregate, mingled foreign matter such as solid dust, or powder dust was not observed at all and also, the effect by the change in the outside air temperature was not observed at all, The dot size was slightly changed by the increase of the plates manufactured but this was within the range of causing any effect. The manufactured plate was subjected to flash fixing in the same manner as above and further to fixing by the irradiation of a halogen lamp (QIR manufactured by Ushio Denki K.K., power demanded: 1.5 kW) and by the spraying of ethyl acetate.

[0318] The halogen lamp was irradiated to perform the heating at a plate surface temperature of 95° C. for 20 seconds. The ethyl acetate was sprayed to a spray amount of 1 g/m². As a result, even after 10,000 sheets were continuously printed, a very clear full color printed matter free of slipping or thinning of the printed image could be obtained. Particularly, in the fixing using a heat roll or a halogen lamp, the fixing time could be greatly shortened by winding a heat insulating material (PET film) around the plate cylinder. In this case, the aluminum substrate was earthed by the contact with an electrically conducting brush (SANDERON, manufactured by Tsuchiya, resistance: about 10 to 1 Ωcm).

EXAMPLE 7

[0319] An operation was performed in the same manner as in Example 4 except for using a paper plate material having provided on the surface thereof a hydrophilic image-receiving layer described below.

[0320] A wood-free paper having a basis weight of 100 g/m² was used as the substrate. On both surfaces of the substrate, a water-resistant layer mainly comprising kaolin and resin components of polyvinyl alcohol, SBR latex and melamine resin was provided and on the thus-obtained paper support, Dispersion Solution A prepared as follows to have a composition shown below was coated to a dry coated amount of 6 g/m², thereby providing an image-receiving layer. This was used as the paper plate material.

[0321] Dispersion Solution A: Dispersion Solution A: Gelatin (extra pure product, produced by  3 g Wako Junyaku) Colloidal silica (Snowtex C, 20% aqueous 20 g solution, produced by Nissan Chemical) Silica gel (Cylisia #310, produced by Fuji  7 g Cylisia Kagaku) Curing agent 0.4 g  Distilled water 100 g 

[0322] These were dispersed together with glass beads in a paint shaker for 10 minutes.

[0323] The obtained printed matter had a very clear image free of slipping or thinning of the printed image even after 10,000 sheets were continuously printed.

[0324] On the other hand, when wood-free paper was used as the printing paper sheet, the solid making was partially failed due to paper dust after 3,000 sheets were printed. Therefore, an air suction pump was disposed as a paper dust-preventing device in the vicinity of the paper feed part and then, printing was performed.

[0325] As a result, printing failure was not generated and the printed matters obtained had a very clear image free of slipping or thinning even after 5,000 sheets were continuously printed. However, after printing of 5,000 sheets, the image of A3 size was elongated by 0.1 mm in the machine direction.

EXAMPLE 8

[0326] An operation was performed in the same manner as in Example 4 except that a plate material having provided on the surface thereof an image-receiving layer capable of hydrophilizing by a desensitization treatment, described below, was used in place of the aluminum plate of Example 4, the non-image area after the preparation of the printing plate was hydrophilized using a plate surface-desensitizing device, the electrically conducting layer of the plate material was earthed by the contact with an electrically conducting plate spring (made of phosphor bronze) at the time of drawing, and the fixing was performed by blowing hot air to the plate material.

[0327] A wood-free paper having a basis weight of 100 g/m² was used as the substrate. On both surfaces of the substrate, a polyethylene film was laminated to a thickness of 20 μm to render the surfaces water-resistant and on this paper support, a coating material for the electrically conducting layer prepared as follows to have a composition shown below was coated to have a dry coated amount of 10 g/m². Thereon, Dispersion Solution B was further coated to have a dry coated weight of 15 g/m², thereby providing an image-receiving layer. This was used as the plate material.

[0328] Coating Material for Electrically Conducting Layer:

[0329] 5.4 Parts of carbon black (30% water solution), 54.6 parts of clay (50% water solution), 36 parts of SBR latex (solid content; 50%, Tg: 25° C.) and 4 parts of melamine resin (Sumirez Resin SR-613, solid content: 80%) were mixed and water was added to make a total solid content of 25%, thereby preparing the coating material.

[0330] Dispersion Solution B:

[0331] A mixture Containing 100 g of dry zinc oxide, 3 g of Binder Resin (B-1) having a structure shown below, 17 g of Binder Resin (B-2) having a structure shown below, 0.15 g of benzoic acid and 155 g of toluene was dispersed using a wet dispersing machine Homogenizer (manufactured by Nippon Seiki K.K.) at a revolution number of 6,000 rpm for 8 minutes.

[0332] Binder Resin (B-1)

[0333] Mw: 9×10³

[0334] Binder Resin (B-2)

[0335] (by weight)

[0336] Mw: 4×10⁴

[0337] The printed matters obtained had a very clear image free of slipping or thinning of the printed image even after 5,000 sheets were continuously printed.

[0338] Comparative Examples were performed in the same manner as in Examples 4 to 8 except for not using a filter 60. In any Comparative Example, the ejection became unstable within several hours to several days and after disorder of image or non-ejection state continued, the ejection port of the head was completely clogged by coarse semisolid aggregate of ink particles at the worst time and the drawing could not be performed.

[0339] According to the present invention, a large number of printed matters having a clear image can be printed. Furthermore, a printing plate having a high-quality image corresponding to the digital image data can be stably manufactured directly on a printing apparatus and the lithographic printing can be performed inexpensively at a high speed. Furthermore, the ink is filtered by a filter, so that a printing plate having a high-quality image can be manufactured.

[0340] While the invention has been described in detail and with reference to specific embodiments thereof, it will be apparent-to one skilled in the art that various changes and modifications can be made therein without departing from the spirit and scope thereof. 

What is claimed is:
 1. A plate-making method comprising: filtering an oil-based ink; forming an image directly on a plate material by an ink jet process comprising ejecting said filtered oil-based ink using electrostatic field based on signals of image data; and fixing said formed image to prepare a printing plate.
 2. The plate-making method according to claim 1 , wherein said oil-based comprises: a nonaqueous solvent having an electric resistivity of 10⁹ Ωcm or more and a dielectric constant of 3.5 or less; and a component dispersed in the nonaqueous solvent, comprising at least resin particles which are solid and are hydrophobic at least at ordinary temperatures.
 3. A plate-making apparatus comprising: an image-forming unit which forms an image directly on a plate material based on signals of image data; and an image-fixing unit which fixes the image formed by said image-forming unit to prepare a printing plate, wherein said image-forming unit comprises an ink jet drawing device having an ejection head which ejects an oil-based ink using electrostatic field and having at least one ink-filtering member provided in a passage of said oil-based ink.
 4. The plate-making apparatus according to claim 3 , wherein said filtering member is provided at a portion immediately preceding an ink ejection part of said ejection head.
 5. The plate-making apparatus according to claim 3 , wherein said filtering member comprises a filter material which blocks coarse aggregates of said oil-based ink and foreign matters including dust mingled during the image formation.
 6. The plate-making apparatus according to claim 5 , wherein said filter material has pores having various shapes and sizes, each of said pores having a minimum distance of not less than 2 μm.
 7. The plate-making apparatus according to claim 5 , wherein said filter material has a single-layer or multilayer structure.
 8. The plate-making apparatus according to claim 7 , wherein said multilayer filter material comprises filter material layers including: a coarsest protective body and a coarsest support provided in an upstream side and a downstream side, respectively: and intervening filter material layers provided between said protective body and support in such a manner that the pore sizes of said intervening filter materials are sequentially reduced toward the downstream side.
 9. The plate-making apparatus according to claim 5 , wherein said filter material has at least one figuration selected from the group consisting of a single plate form, a tea strainer form, a coming back form and a cylinder form.
 10. The plate-making apparatus according to claim 5 , wherein said filter material comprises at least one material selected from the group consisting of paper, plastic, metal, ceramic and glass.
 11. The plate-making apparatus according to claim 5 , wherein said filter material is of cartridge-type and exchangeable.
 12. The plate-making apparatus according to claim 5 , further comprising a filter material accumulation-removing member which removes substances accumulated on said filter material.
 13. The plate-making apparatus according to claim 12 , wherein said removal of the filter material accumulation is performed by at least one of ultrasonic irradiation, vibration, and back flow of said ink or a cleaning solution.
 14. The plate-making apparatus according to claim 3 , wherein said filtering member comprises at least one filtering system selected from the group consisting of gravity filtration, pressure filtration, vacuum filtration and constant rate filtration.
 15. The plate-making apparatus according to claim 3 , wherein said oil-based ink comprises: a nonaqueous solvent having an electric resistivity of 10⁹ Ωcm or more and a dielectric constant of 3.5 or less; and a component dispersed in the nonaqueous solvent, comprising at least resin particles which are solid and are hydrophobic at least at ordinary temperatures.
 16. The plate-making apparatus according to claim 3 , wherein said image-fixing unit has a heating member comprising at least one of a heat roller, an infrared lamp, a halogen lamp and a xenon lamp.
 17. A computer-to-cylinder type lithographic printing method comprising: mounting a plate material onto a plate cylinder of a printing apparatus; filtering an oil-based ink; forming an image directly on said plate material by an ink jet process comprising ejecting said filtered oil-based ink from an ejection head using electrostatic field based on signals of image data; fixing said image to prepare a printing plate; and performing lithographic printing with said printing plate.
 18. The computer-to-cylinder type lithographic printing process according to claim 17 , wherein said oil-based ink comprises: a nonaqueous solvent having an electric resistivity of 10⁹ Ωcm or more and a dielectric constant of 3.5 or less; and a component dispersed in the nonaqueous solvent, comprising at least resin particles which are solid and are hydrophobic at least at ordinary temperatures.
 19. A computer-to-cylinder type lithographic printing apparatus comprising: a plate cylinder; an image-forming unit which directly forms an image on a plate material mounted onto said plate cylinder based on signals of image data; an image-fixing unit which fixes the image formed by said image-forming unit to prepare a printing plate; and a lithographic printing unit which performs lithographic printing with the printing plate, wherein said image-forming unit comprises an ink jet drawing device having an ejection head which ejects an oil-based ink using electrostatic field and having at least one ink filtering member provided in a passage of said oil-based ink.
 20. The computer-to-cylinder type lithographic printing apparatus according to claim 19 , wherein said filtering member is provided at a portion immediately preceding an ink ejection part of said ejection head.
 21. The computer-to-cylinder type lithographic printing apparatus according to claim 19 , wherein said filtering member comprising a filter material which blocks coarse aggregates of said ink and foreign matters including dust mingled during the image formation.
 22. The computer-to-cylinder type lithographic printing apparatus according to claim 21 , wherein said filter material has pores having various shapes and sizes, each of said pores having a minimum distance of not less than 2 μm.
 23. The computer-to-cylinder type lithographic printing apparatus according to claim 21 , wherein said filter material has a single-layer or multilayer structure.
 24. The computer-to-cylinder type lithographic printing apparatus according to claim 23 , wherein said multilayer filter material comprises filter material layers including: a coarsest protective body and a coarsest support provided in an upstream side and a downstream side, respectively; and intervening filter material layers provided between said protective body and support in such a manner that the pore sizes of said intervening filter materials are sequentially reduced toward the downstream side.
 25. The computer-to-cylinder type lithographic printing apparatus according to claim 21 , wherein said filter material has at least one figuration selected from the group consisting of a single plate form, a tea strainer form, a coming back form and a cylinder form.
 26. The computer-to-cylinder type lithographic printing apparatus according to claim 21 , wherein said filter material comprises at least one material selected from the group consisting of paper, plastic, metal, ceramic and glass.
 27. The computer-to-cylinder type lithographic printing apparatus according to claim 21 , wherein said filter material is of cartridge-type and exchangeable.
 28. The computer-to-cylinder type lithographic printing apparatus according to claim 21 , further comprising a filter material accumulation-removing member which removes substances accumulated on said filter material.
 29. The computer-to-cylinder type lithographic printing apparatus according to claim 28 , wherein said removal of the filter material accumulation is performed by at least one of ultrasonic irradiation, vibration, and back flow of said ink or a cleaning solution.
 30. The computer-to-cylinder type lithographic printing apparatus according to claim 19 , wherein said filtering member comprises at least one filtering system selected from the group consisting of gravity filtration, pressure filtration, vacuum filtration and constant rate filtration.
 31. The computer-to-cylinder type lithographic printing apparatus according to claim 19 , wherein said oil-based ink comprises: a nonaqueous solvent having an electric resistivity of 10⁹ Ωcm or more and a dielectric constant of 3.5 or less; and a component dispersed in the nonaqueous solvent, comprising at least resin particles which are solid and are hydrophobic at least at ordinary temperatures. 